Journal of Materials Chemistry A, volume 11, issue 12, pages 6543-6555

Sodiation energetics in pore size controlled hard carbons determined via entropy profiling†

Michael Peter Mercer 1, 2, 3
Mangayarkarasi Nagarathinam 2, 3
E. M. Gavilán-Arriazu 4, 5
Anshika Binjrajka 2
Swoyam Panda 2
Heather-Jane Au 6
Maria Crespo Ribadeneyra 6, 7
Ezequiel P. Leiva 4
Harry Hoster 2, 3, 8
3
 
The Faraday Institution, Quad One, Harwell Science and Innovation Campus, Didcot, UK
4
 
Departamento de Química Teórica Y Computacional, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, INFIQC, Córdoba, Argentina
5
 
Facultad de Matemática, Astronomía y Física, IFEG-CONICET, Universidad Nacional de Córdoba, Córdoba, Argentina
Publication typeJournal Article
Publication date2023-02-24
Q1
Q1
SJR2.804
CiteScore19.5
Impact factor10.7
ISSN20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract

Cell temperature of hard carbons is varied under open circuit conditions (entropy profiling) during sodiation. Features vary with pore size, revealing the nanopore filling onset. Sodium binding energy scales inversely with pore curvature radius.

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Mercer M. P. et al. Sodiation energetics in pore size controlled hard carbons determined via entropy profiling† // Journal of Materials Chemistry A. 2023. Vol. 11. No. 12. pp. 6543-6555.
GOST all authors (up to 50) Copy
Mercer M. P., Nagarathinam M., Gavilán-Arriazu E. M., Binjrajka A., Panda S., Au H., Crespo Ribadeneyra M., Titirici M., Leiva E. P., Hoster H. Sodiation energetics in pore size controlled hard carbons determined via entropy profiling† // Journal of Materials Chemistry A. 2023. Vol. 11. No. 12. pp. 6543-6555.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/d2ta09406a
UR - https://doi.org/10.1039/d2ta09406a
TI - Sodiation energetics in pore size controlled hard carbons determined via entropy profiling†
T2 - Journal of Materials Chemistry A
AU - Mercer, Michael Peter
AU - Nagarathinam, Mangayarkarasi
AU - Gavilán-Arriazu, E. M.
AU - Binjrajka, Anshika
AU - Panda, Swoyam
AU - Au, Heather-Jane
AU - Crespo Ribadeneyra, Maria
AU - Titirici, Magda
AU - Leiva, Ezequiel P.
AU - Hoster, Harry
PY - 2023
DA - 2023/02/24
PB - Royal Society of Chemistry (RSC)
SP - 6543-6555
IS - 12
VL - 11
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2023_Mercer,
author = {Michael Peter Mercer and Mangayarkarasi Nagarathinam and E. M. Gavilán-Arriazu and Anshika Binjrajka and Swoyam Panda and Heather-Jane Au and Maria Crespo Ribadeneyra and Magda Titirici and Ezequiel P. Leiva and Harry Hoster},
title = {Sodiation energetics in pore size controlled hard carbons determined via entropy profiling†},
journal = {Journal of Materials Chemistry A},
year = {2023},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/d2ta09406a},
number = {12},
pages = {6543--6555},
doi = {10.1039/d2ta09406a}
}
MLA
Cite this
MLA Copy
Mercer, Michael Peter, et al. “Sodiation energetics in pore size controlled hard carbons determined via entropy profiling†.” Journal of Materials Chemistry A, vol. 11, no. 12, Feb. 2023, pp. 6543-6555. https://doi.org/10.1039/d2ta09406a.
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