,
pages 531-535
Far-infrared study of palladium(II )–halogen complexes with chelating ligands containing nitrogen and σ carbon as donor atoms
Publication type: Journal Article
Publication date: 1970-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00224944
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
I.r. spectra of palladium(II) halogeno-bridged complexes of the type [Pd(N–C)X]2= azobenzene-2-C,N; NN-dimethylbenzylamine-2-C,N; and 2-methoxy-3-NN-dimethylaminopropyl; X = Cl or (Br) have been recorded in the range (600–120 cm.–1). The bridging-halogen stretching frequencies are discussed on the basis of a planar asymmetric Pd[graphic omitted]Pd unit.Bridge-splitting reactions with mono- and bi-dentate ligands bearing nitrogen or phosphorous as donor atoms are reported and the structures of the resulting products are interpretated on the basis of their far-i.r. spectra. We have also established that the v(Pd–Cl) frequency in the products in the range 300–280 cm.–1 with chloride in the trans-position to the phenyl or alkyl groups.
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Total citations:
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Citations from 2024:
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(2.33%)
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GOST
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Crociani B. et al. Far-infrared study of palladium(II)–halogen complexes with chelating ligands containing nitrogen and σ carbon as donor atoms // Journal of the Chemical Society A Inorganic Physical Theoretical. 1970. pp. 531-535.
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Crociani B., Boschi T., Pietropaolo R., Belluco U. Far-infrared study of palladium(II)–halogen complexes with chelating ligands containing nitrogen and σ carbon as donor atoms // Journal of the Chemical Society A Inorganic Physical Theoretical. 1970. pp. 531-535.
Cite this
RIS
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TY - JOUR
DO - 10.1039/j19700000531
UR - https://doi.org/10.1039/j19700000531
TI - Far-infrared study of palladium(II)–halogen complexes with chelating ligands containing nitrogen and σ carbon as donor atoms
T2 - Journal of the Chemical Society A Inorganic Physical Theoretical
AU - Crociani, B.
AU - Boschi, T.
AU - Pietropaolo, R
AU - Belluco, U
PY - 1970
DA - 1970/01/01
PB - Royal Society of Chemistry (RSC)
SP - 531-535
SN - 0022-4944
ER -
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@article{1970_Crociani,
author = {B. Crociani and T. Boschi and R Pietropaolo and U Belluco},
title = {Far-infrared study of palladium(II)–halogen complexes with chelating ligands containing nitrogen and σ carbon as donor atoms},
journal = {Journal of the Chemical Society A Inorganic Physical Theoretical},
year = {1970},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/j19700000531},
pages = {531--535},
doi = {10.1039/j19700000531}
}