Alternatives to α-diazo ketones for tandem cyclization–cycloaddition and carbenoid–alkyne metathesis strategies. Novel cyclic enol–ether formation via carbonyl ylide rearrangement reactions
Тип публикации: Journal Article
Дата публикации: 1992-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 0300922X, 13645463, 14727781
General Medicine
Краткое описание
Attempts to form carbonyl ylides from free carbenes derived from diazirines or diazo compounds lacking electron-withdrawing substituents resulted in azine formation or Wolff rearrangement, respectively, lodonium ylides proved to be a possible alternative to α-diazo compounds for metallocarbenoid generation, similar reactivity being observed for both systems. Studies into the rearrangement chemistry of carbonyl ylides provided a novel cyclic enol–ether synthesis via a 1,4-hydrogen shift process.
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Fairfax D. J. et al. Alternatives to α-diazo ketones for tandem cyclization–cycloaddition and carbenoid–alkyne metathesis strategies. Novel cyclic enol–ether formation via carbonyl ylide rearrangement reactions // Journal of the Chemical Society Perkin Transactions 1. 1992. Vol. 21. pp. 2837-2844.
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Fairfax D. J., Austin D. J., Xu S. L., Padwa A. Alternatives to α-diazo ketones for tandem cyclization–cycloaddition and carbenoid–alkyne metathesis strategies. Novel cyclic enol–ether formation via carbonyl ylide rearrangement reactions // Journal of the Chemical Society Perkin Transactions 1. 1992. Vol. 21. pp. 2837-2844.
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TY - JOUR
DO - 10.1039/P19920002837
UR - https://doi.org/10.1039/P19920002837
TI - Alternatives to α-diazo ketones for tandem cyclization–cycloaddition and carbenoid–alkyne metathesis strategies. Novel cyclic enol–ether formation via carbonyl ylide rearrangement reactions
T2 - Journal of the Chemical Society Perkin Transactions 1
AU - Fairfax, David J.
AU - Austin, David J
AU - Xu, Simon L
AU - Padwa, Albert
PY - 1992
DA - 1992/01/01
PB - Royal Society of Chemistry (RSC)
SP - 2837-2844
IS - 21
SN - 0300-922X
SN - 1364-5463
SN - 1472-7781
ER -
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@article{1992_Fairfax,
author = {David J. Fairfax and David J Austin and Simon L Xu and Albert Padwa},
title = {Alternatives to α-diazo ketones for tandem cyclization–cycloaddition and carbenoid–alkyne metathesis strategies. Novel cyclic enol–ether formation via carbonyl ylide rearrangement reactions},
journal = {Journal of the Chemical Society Perkin Transactions 1},
year = {1992},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/P19920002837},
number = {21},
pages = {2837--2844},
doi = {10.1039/P19920002837}
}