Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices

Evgeny N Ushakov
Alexei Buevich
Alexei V. Buevich
Igor I Baskin
Olga A Fedorova
Artem I. Vedernikov
Michael V Alfimov
Bertil Eliasson
Ulf Edlund
Publication typeJournal Article
Publication date1999-01-01
SJR
CiteScore
Impact factor
ISSN03009580, 13645471, 1472779X
General Environmental Science
General Earth and Planetary Sciences
Abstract
The s-conformations of trans-1b–e were studied by 1H NMR spectroscopy in CD3CN solution. It was shown that in trans-1b–e intramolecular ion pairs between the SO3– group and the positively charged nitrogen atom of the benzothiazolium residue are formed. In the case of trans-1a no ionic association was observed. The complex formation of the trans- and cis-isomers of crown-containing styryl dyes with Mg2+ in CH3CN was studied spectrophotometrically. The anion-“capped” complexes formed by the cis-isomers were found to be more stable than the complexes formed by the corresponding trans-isomers. The stability constants of the complexes formed by the cis-isomers depend markedly on length and type of the N-substituent. Data from PM3 quantum-chemical calculations were used for the interpretation of some experimental data.
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Ushakov E. et al. Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 3. pp. 601-608.
GOST all authors (up to 50) Copy
Ushakov E., Ushakov E. N., Gromov S. P., Buevich A., Buevich A. V., Baskin I. I., Федорова О. С., Fedorova O. A., Vedernikov A. I., Alfimov M. V., Eliasson B., Edlund U. Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 3. pp. 601-608.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/a807565d
UR - https://xlink.rsc.org/?DOI=a807565d
TI - Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices
T2 - Journal of the Chemical Society Perkin Transactions 2
AU - Ushakov, E.N.
AU - Ushakov, Evgeny N
AU - Gromov, Sergei P.
AU - Buevich, Alexei
AU - Buevich, Alexei V.
AU - Baskin, Igor I
AU - Федорова, О. С.
AU - Fedorova, Olga A
AU - Vedernikov, Artem I.
AU - Alfimov, Michael V
AU - Eliasson, Bertil
AU - Edlund, Ulf
PY - 1999
DA - 1999/01/01
PB - Royal Society of Chemistry (RSC)
SP - 601-608
IS - 3
SN - 0300-9580
SN - 1364-5471
SN - 1472-779X
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{1999_Ushakov,
author = {E.N. Ushakov and Evgeny N Ushakov and Sergei P. Gromov and Alexei Buevich and Alexei V. Buevich and Igor I Baskin and О. С. Федорова and Olga A Fedorova and Artem I. Vedernikov and Michael V Alfimov and Bertil Eliasson and Ulf Edlund},
title = {Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices},
journal = {Journal of the Chemical Society Perkin Transactions 2},
year = {1999},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=a807565d},
number = {3},
pages = {601--608},
doi = {10.1039/a807565d}
}