Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices
Тип публикации: Journal Article
Дата публикации: 1999-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 03009580, 13645471, 1472779X
General Environmental Science
General Earth and Planetary Sciences
Краткое описание
The s-conformations of trans-1b–e were studied by 1H NMR spectroscopy in CD3CN solution. It was shown that in trans-1b–e intramolecular ion pairs between the SO3– group and the positively charged nitrogen atom of the benzothiazolium residue are formed. In the case of trans-1a no ionic association was observed. The complex formation of the trans- and cis-isomers of crown-containing styryl dyes with Mg2+ in CH3CN was studied spectrophotometrically. The anion-“capped” complexes formed by the cis-isomers were found to be more stable than the complexes formed by the corresponding trans-isomers. The stability constants of the complexes formed by the cis-isomers depend markedly on length and type of the N-substituent. Data from PM3 quantum-chemical calculations were used for the interpretation of some experimental data.
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Ushakov E. et al. Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 3. pp. 601-608.
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Ushakov E., Ushakov E. N., Gromov S. P., Buevich A., Buevich A. V., Baskin I. I., Федорова О. С., Fedorova O. A., Vedernikov A. I., Alfimov M. V., Eliasson B., Edlund U. Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 3. pp. 601-608.
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TY - JOUR
DO - 10.1039/a807565d
UR - https://xlink.rsc.org/?DOI=a807565d
TI - Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices
T2 - Journal of the Chemical Society Perkin Transactions 2
AU - Ushakov, E.N.
AU - Ushakov, Evgeny N
AU - Gromov, Sergei P.
AU - Buevich, Alexei
AU - Buevich, Alexei V.
AU - Baskin, Igor I
AU - Федорова, О. С.
AU - Fedorova, Olga A
AU - Vedernikov, Artem I.
AU - Alfimov, Michael V
AU - Eliasson, Bertil
AU - Edlund, Ulf
PY - 1999
DA - 1999/01/01
PB - Royal Society of Chemistry (RSC)
SP - 601-608
IS - 3
SN - 0300-9580
SN - 1364-5471
SN - 1472-779X
ER -
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@article{1999_Ushakov,
author = {E.N. Ushakov and Evgeny N Ushakov and Sergei P. Gromov and Alexei Buevich and Alexei V. Buevich and Igor I Baskin and О. С. Федорова and Olga A Fedorova and Artem I. Vedernikov and Michael V Alfimov and Bertil Eliasson and Ulf Edlund},
title = {Crown-containing styryl dyes: Cation-induced self-assembly of multiphotochromic 15-crown-5 ethers into photoswitchable molecular devices},
journal = {Journal of the Chemical Society Perkin Transactions 2},
year = {1999},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=a807565d},
number = {3},
pages = {601--608},
doi = {10.1039/a807565d}
}