Photoswitchable molecular pincers: Synthesis, self-assembly into sandwich complexes and ion-selective intramolecular [2+2]-photocycloaddition of an unsaturated bis-15-crown-5 ether
Тип публикации: Journal Article
Дата публикации: 1999-01-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 03009580, 13645471, 1472779X
General Environmental Science
General Earth and Planetary Sciences
Краткое описание
Bis-crown-containing styryl dyes (E,E)-2a,b having the structure and properties of molecular pincers were synthesised. In acetonitrile solution, dye (E,E)-2b is able to form intramolecular sandwich complexes with Ca2+ and Ba2+ cations. These complexes undergo E–Z-photoisomerisation and intramolecular stereoselective [2+2]-photocycloaddition to afford cyclobutane derivatives 6a,b, whose structures were studied by 1H NMR spectroscopy. Molecular-mechanics and semiempirical quantum-chemical calculations were performed to interpret experimental data.
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Gromov S. P. et al. Photoswitchable molecular pincers: Synthesis, self-assembly into sandwich complexes and ion-selective intramolecular [2+2]-photocycloaddition of an unsaturated bis-15-crown-5 ether // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 7. pp. 1323-1330.
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Gromov S. P., Федорова О. С., Fedorova O. A., Ushakov E., Ushakov E. N., Buevich A., Buevich A. V., Baskin I. I., Pershina Y. V., Eliasson B., Edlund U., Alfimov M. V. Photoswitchable molecular pincers: Synthesis, self-assembly into sandwich complexes and ion-selective intramolecular [2+2]-photocycloaddition of an unsaturated bis-15-crown-5 ether // Journal of the Chemical Society Perkin Transactions 2. 1999. Vol. 7. pp. 1323-1330.
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TY - JOUR
DO - 10.1039/a902151e
UR - https://xlink.rsc.org/?DOI=a902151e
TI - Photoswitchable molecular pincers: Synthesis, self-assembly into sandwich complexes and ion-selective intramolecular [2+2]-photocycloaddition of an unsaturated bis-15-crown-5 ether
T2 - Journal of the Chemical Society Perkin Transactions 2
AU - Gromov, Sergei P.
AU - Федорова, О. С.
AU - Fedorova, Olga A
AU - Ushakov, E.N.
AU - Ushakov, Evgeny N
AU - Buevich, Alexei
AU - Buevich, Alexei V.
AU - Baskin, Igor I
AU - Pershina, Yuliya V
AU - Eliasson, Bertil
AU - Edlund, Ulf
AU - Alfimov, Michael V
PY - 1999
DA - 1999/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1323-1330
IS - 7
SN - 0300-9580
SN - 1364-5471
SN - 1472-779X
ER -
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@article{1999_Gromov,
author = {Sergei P. Gromov and О. С. Федорова and Olga A Fedorova and E.N. Ushakov and Evgeny N Ushakov and Alexei Buevich and Alexei V. Buevich and Igor I Baskin and Yuliya V Pershina and Bertil Eliasson and Ulf Edlund and Michael V Alfimov},
title = {Photoswitchable molecular pincers: Synthesis, self-assembly into sandwich complexes and ion-selective intramolecular [2+2]-photocycloaddition of an unsaturated bis-15-crown-5 ether},
journal = {Journal of the Chemical Society Perkin Transactions 2},
year = {1999},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=a902151e},
number = {7},
pages = {1323--1330},
doi = {10.1039/a902151e}
}