A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement
Тип публикации: Journal Article
Дата публикации: 2001-01-01
scimago Q2
wos Q2
БС2
SJR: 0.698
CiteScore: 5.3
Impact factor: 2.9
ISSN: 14639076, 14639084
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
The
kinetics of the reactions of hydrogen atoms with aliphatic alcohols in aqueous solution were studied by pulse
radiolysis. The rate constants for the reaction of hydrogen atoms with methanol, ethanol, 2-propanol and
tert-butyl alcohol were determined from the increase in optical absorption in the UV region to be 1.1 × 106,
1.75 × 107, 5.3 × 107 and 2.3 × 105 dm3
mol−1 s−1, respectively. The bimolecular decay rate constants
of the first two
alcohol radicals were
evaluated to be 2.4 × 109 and 1.5 × 109 dm3 mol−1 s−1.
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Alam M. S., Rao B. S. M., Janata E. A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement // Physical Chemistry Chemical Physics. 2001. Vol. 3. No. 13. pp. 2622-2624.
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Alam M. S., Rao B. S. M., Janata E. A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement // Physical Chemistry Chemical Physics. 2001. Vol. 3. No. 13. pp. 2622-2624.
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TY - JOUR
DO - 10.1039/b101385h
UR - https://doi.org/10.1039/b101385h
TI - A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement
T2 - Physical Chemistry Chemical Physics
AU - Alam, M. S.
AU - Rao, B S M
AU - Janata, E.
PY - 2001
DA - 2001/01/01
PB - Royal Society of Chemistry (RSC)
SP - 2622-2624
IS - 13
VL - 3
SN - 1463-9076
SN - 1463-9084
ER -
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BibTex (до 50 авторов)
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@article{2001_Alam,
author = {M. S. Alam and B S M Rao and E. Janata},
title = {A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement},
journal = {Physical Chemistry Chemical Physics},
year = {2001},
volume = {3},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/b101385h},
number = {13},
pages = {2622--2624},
doi = {10.1039/b101385h}
}
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MLA
Скопировать
Alam, M. S., et al. “A pulse radiolysis study of H atom reactions with aliphatic alcohols: evaluation of kinetics by direct optical absorption measurement.” Physical Chemistry Chemical Physics, vol. 3, no. 13, Jan. 2001, pp. 2622-2624. https://doi.org/10.1039/b101385h.