Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems
Тип публикации: Journal Article
Дата публикации: 2002-04-12
SJR: 0.791
CiteScore: —
Impact factor: —
ISSN: 03009580, 13645471, 1472779X
General Environmental Science
General Earth and Planetary Sciences
Краткое описание
X-Ray studies of a series of 1-ethynyl-8-methoxynaphthalenes with varying functional groups at the alkyne terminus show only small changes in the 1,5 MeO⋯spC contact distances (2.593–2.663 A) despite the different through-bond electron-attracting powers of the terminal substituents. Replacement of methoxy with dimethylamino led to a chemical reaction when the alkyne's activating group was a carboxylic ester. The 1,5 N⋯spC interaction between a dimethylamino group and a triphenylsilylethyne group has a 1,5 Me2N⋯spC contact distance ca. 0.12 A longer than for the corresponding methoxy case, indicative of a primarily steric interaction.
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ГОСТ
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BELL P. C. et al. Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems // Journal of the Chemical Society Perkin Transactions 2. 2002. Vol. 5. pp. 878-886.
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BELL P. C., Skranc W., Formosa X., O'Leary J., Wallis J. D. Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems // Journal of the Chemical Society Perkin Transactions 2. 2002. Vol. 5. pp. 878-886.
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TY - JOUR
DO - 10.1039/b201038k
UR - https://doi.org/10.1039/b201038k
TI - Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems
T2 - Journal of the Chemical Society Perkin Transactions 2
AU - BELL, PAUL C.
AU - Skranc, Wolfgang
AU - Formosa, Xavier
AU - O'Leary, Jane
AU - Wallis, J. D.
PY - 2002
DA - 2002/04/12
PB - Royal Society of Chemistry (RSC)
SP - 878-886
IS - 5
SN - 0300-9580
SN - 1364-5471
SN - 1472-779X
ER -
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@article{2002_BELL,
author = {PAUL C. BELL and Wolfgang Skranc and Xavier Formosa and Jane O'Leary and J. D. Wallis},
title = {Interactions between alkynes and methoxy or dimethylamino groups in peri-naphthalene systems},
journal = {Journal of the Chemical Society Perkin Transactions 2},
year = {2002},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/b201038k},
number = {5},
pages = {878--886},
doi = {10.1039/b201038k}
}
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