Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexesElectronic supplementary information (ESI) available: 1H NMR spectrum of {SmIII(Pc)[Pc(OC5H11)4]}– in CDCl3/DMSO-d6 (1∶1) in the presence of a few drops of hydrazine hydrate. See http://www.rsc.org/suppdata/cc/b3/b301139a/
Тип публикации: Journal Article
Дата публикации: 2003-04-17
scimago Q1
wos Q2
БС1
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
12778731
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
Treatment of MIII(Pc)(acac) (M = Sm, Eu, Gd; Pc = phthalocyaninate; acac = acetylacetonate), generated in situ, with 3-(3-pentyloxy)phthalonitrile in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) in n-pentanol affords racemic mixtures of the chiral double-deckers MIII(Pc)[Pc(OC5H11)4] [Pc(OC5H11)4 = 1,8,15,22-tetrakis(3-pentyloxy)phthalocyaninate], which have been spectroscopically and structurally characterised.
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Bian Y. et al. Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexesElectronic supplementary information (ESI) available: 1H NMR spectrum of {SmIII(Pc)[Pc(OC5H11)4]}– in CDCl3/DMSO-d6 (1∶1) in the presence of a few drops of hydrazine hydrate. See http://www.rsc.org/suppdata/cc/b3/b301139a/ // Chemical Communications. 2003. Vol. 10. pp. 1194-1195.
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Bian Y., Wang R., Jiang J., Lee C., Wang J., Ng D. K. Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexesElectronic supplementary information (ESI) available: 1H NMR spectrum of {SmIII(Pc)[Pc(OC5H11)4]}– in CDCl3/DMSO-d6 (1∶1) in the presence of a few drops of hydrazine hydrate. See http://www.rsc.org/suppdata/cc/b3/b301139a/ // Chemical Communications. 2003. Vol. 10. pp. 1194-1195.
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TY - JOUR
DO - 10.1039/b301139a
UR - https://doi.org/10.1039/b301139a
TI - Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexesElectronic supplementary information (ESI) available: 1H NMR spectrum of {SmIII(Pc)[Pc(OC5H11)4]}– in CDCl3/DMSO-d6 (1∶1) in the presence of a few drops of hydrazine hydrate. See http://www.rsc.org/suppdata/cc/b3/b301139a/
T2 - Chemical Communications
AU - Bian, Yongzhong
AU - Wang, Rongming
AU - Jiang, Jianzhuang
AU - Lee, Chi-Hang
AU - Wang, Jin-Zhi
AU - Ng, Dennis KP
PY - 2003
DA - 2003/04/17
PB - Royal Society of Chemistry (RSC)
SP - 1194-1195
IS - 10
PMID - 12778731
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2003_Bian,
author = {Yongzhong Bian and Rongming Wang and Jianzhuang Jiang and Chi-Hang Lee and Jin-Zhi Wang and Dennis KP Ng},
title = {Synthesis, spectroscopic characterisation and structure of the first chiral heteroleptic bis(phthalocyaninato) rare earth complexesElectronic supplementary information (ESI) available: 1H NMR spectrum of {SmIII(Pc)[Pc(OC5H11)4]}– in CDCl3/DMSO-d6 (1∶1) in the presence of a few drops of hydrazine hydrate. See http://www.rsc.org/suppdata/cc/b3/b301139a/},
journal = {Chemical Communications},
year = {2003},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/b301139a},
number = {10},
pages = {1194--1195},
doi = {10.1039/b301139a}
}