,  том 2 ,  издание 23 ,  страницы 3442

Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations

Тип публикации: Journal Article
Дата публикации: 2004-11-05
SCImago Q2
WOS Q2
БС1
SJR: 0.475
CiteScore: 4.8
Impact factor: 2.8
ISSN: 14770520, 14770539
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
The boron trifluoride-catalyzed Rothemund condensations of phenylpropargylaldehyde with 4,7-dihydro-4,7-ethano-2H-isoindole or 3,4-diethylpyrrole in dichloromethane at low temperature give 5,10,15,20-tetrakis(phenylethynyl)porphyrins bearing bicyclo[2.2.2]octadiene and octaethyl substituents, respectively. The former undergoes a retro Diels-Alder reaction to afford 5,10,15,20-tetrakis(phenylethynyl)benzoporphyrin quantitatively. The different conformations of the porphyrin periphery were determined by X-ray diffraction and their redox and spectroscopic properties have been investigated.
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ГОСТ |
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Shen Z. et al. Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations // Organic and Biomolecular Chemistry. 2004. Vol. 2. No. 23. p. 3442.
ГОСТ со всеми авторами (до 50) Скопировать
Shen Z., Uno H., Shimizu Y., Ono N. Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations // Organic and Biomolecular Chemistry. 2004. Vol. 2. No. 23. p. 3442.
RIS |
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TY - JOUR
DO - 10.1039/b412688b
UR - https://doi.org/10.1039/b412688b
TI - Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations
T2 - Organic and Biomolecular Chemistry
AU - Shen, Zhen-zhou
AU - Uno, Hidemitsu
AU - Shimizu, Yusuke
AU - Ono, Noboru
PY - 2004
DA - 2004/11/05
PB - Royal Society of Chemistry (RSC)
SP - 3442
IS - 23
VL - 2
PMID - 15565235
SN - 1477-0520
SN - 1477-0539
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2004_Shen,
author = {Zhen-zhou Shen and Hidemitsu Uno and Yusuke Shimizu and Noboru Ono},
title = {Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations},
journal = {Organic and Biomolecular Chemistry},
year = {2004},
volume = {2},
publisher = {Royal Society of Chemistry (RSC)},
month = {nov},
url = {https://doi.org/10.1039/b412688b},
number = {23},
pages = {3442},
doi = {10.1039/b412688b}
}
MLA
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Shen, Zhen-zhou, et al. “Controlling conformations and physical properties of meso-tetrakis(phenylethynyl)porphyrins by ring fusion: synthesis, properties and structural characterizations.” Organic and Biomolecular Chemistry, vol. 2, no. 23, Nov. 2004, p. 3442. https://doi.org/10.1039/b412688b.
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