issue 18 pages 2366

Evolution of the pseudo-1,3-dipolar cycloaddition chemistry of SNSMF6(M = As, Sb) leading to 2,5-dihydroxybenzo-1,3,2-dithiazolylium and 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium salts and their corresponding radicals

Publication typeJournal Article
Publication date2005-03-15
scimago Q1
wos Q2
SJR1.037
CiteScore7.4
Impact factor4.2
ISSN13597345, 1364548X
PubMed ID:  15877130
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
We report the unprecedented formation of a benzo-fused 1,3,2-dithiazolylium [AsF6-] salt by a one step, quantitative, cycloaddition of SNSAsF6 with 1,4-benzoquinone. In contrast, the reaction of SNSSbF6 with 1,4-naphthaquinone results in 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium [SbF6-]. Both were reduced to the corresponding 7pi radicals.
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Decken A. et al. Evolution of the pseudo-1,3-dipolar cycloaddition chemistry of SNSMF6(M = As, Sb) leading to 2,5-dihydroxybenzo-1,3,2-dithiazolylium and 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium salts and their corresponding radicals // Chemical Communications. 2005. Vol. 18. p. 2366.
GOST all authors (up to 50) Copy
Decken A., Mailman A., Mattar S. M., Passmore J. Evolution of the pseudo-1,3-dipolar cycloaddition chemistry of SNSMF6(M = As, Sb) leading to 2,5-dihydroxybenzo-1,3,2-dithiazolylium and 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium salts and their corresponding radicals // Chemical Communications. 2005. Vol. 18. p. 2366.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/b418137a
UR - https://doi.org/10.1039/b418137a
TI - Evolution of the pseudo-1,3-dipolar cycloaddition chemistry of SNSMF6(M = As, Sb) leading to 2,5-dihydroxybenzo-1,3,2-dithiazolylium and 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium salts and their corresponding radicals
T2 - Chemical Communications
AU - Decken, Andreas
AU - Mailman, Aaron
AU - Mattar, S. M.
AU - Passmore, Jack
PY - 2005
DA - 2005/03/15
PB - Royal Society of Chemistry (RSC)
SP - 2366
IS - 18
PMID - 15877130
SN - 1359-7345
SN - 1364-548X
ER -
BibTex
Cite this
BibTex (up to 50 authors) Copy
@article{2005_Decken,
author = {Andreas Decken and Aaron Mailman and S. M. Mattar and Jack Passmore},
title = {Evolution of the pseudo-1,3-dipolar cycloaddition chemistry of SNSMF6(M = As, Sb) leading to 2,5-dihydroxybenzo-1,3,2-dithiazolylium and 2,7-dicarbonylnaphtha-1,3,2-dithiazolylium salts and their corresponding radicals},
journal = {Chemical Communications},
year = {2005},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://doi.org/10.1039/b418137a},
number = {18},
pages = {2366},
doi = {10.1039/b418137a}
}
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