Palladium catalysed aryl amination reactions in supercritical carbon dioxide
Тип публикации: Journal Article
Дата публикации: 2005-09-13
SCImago Q2
WOS Q2
БС1
SJR: 0.475
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
16211113
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
Palladium catalysed C-N bond formation in supercritical carbon dioxide has been accomplished. Carbamic acid formation is avoided in part through the use of an N-silylamine as the coupling partner. Employing a catalyst system of Pd2dba3(1 mol%) and 2-dicyclohexylphosphino-2',4',6'-triisopropyl-1,1'-biphenyl (X-Phos)(2 mol%) enabled the catalytic amination of aryl bromides and chlorides with N-silylanilines to be realised in excellent yield. Extension of the methodology to the N-arylation of N-silyldiarylamines, N-silylazoles and N-silylsulfonamides is reported.
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ГОСТ
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Smith C. J. et al. Palladium catalysed aryl amination reactions in supercritical carbon dioxide // Organic and Biomolecular Chemistry. 2005. Vol. 3. No. 20. p. 3767.
ГОСТ со всеми авторами (до 50)
Скопировать
Smith C. J., Tsang M. W. S., Holmes A. R., Danheiser R. L., Tester J. W. Palladium catalysed aryl amination reactions in supercritical carbon dioxide // Organic and Biomolecular Chemistry. 2005. Vol. 3. No. 20. p. 3767.
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RIS
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TY - JOUR
DO - 10.1039/b509345g
UR - https://doi.org/10.1039/b509345g
TI - Palladium catalysed aryl amination reactions in supercritical carbon dioxide
T2 - Organic and Biomolecular Chemistry
AU - Smith, Catherine J
AU - Tsang, Melanie W S
AU - Holmes, Andrew R.
AU - Danheiser, Rick L
AU - Tester, Jefferson W
PY - 2005
DA - 2005/09/13
PB - Royal Society of Chemistry (RSC)
SP - 3767
IS - 20
VL - 3
PMID - 16211113
SN - 1477-0520
SN - 1477-0539
ER -
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BibTex (до 50 авторов)
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@article{2005_Smith,
author = {Catherine J Smith and Melanie W S Tsang and Andrew R. Holmes and Rick L Danheiser and Jefferson W Tester},
title = {Palladium catalysed aryl amination reactions in supercritical carbon dioxide},
journal = {Organic and Biomolecular Chemistry},
year = {2005},
volume = {3},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/b509345g},
number = {20},
pages = {3767},
doi = {10.1039/b509345g}
}
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MLA
Скопировать
Smith, Catherine J., et al. “Palladium catalysed aryl amination reactions in supercritical carbon dioxide.” Organic and Biomolecular Chemistry, vol. 3, no. 20, Sep. 2005, p. 3767. https://doi.org/10.1039/b509345g.
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