Chemical Communications

, issue 44 , pages 5758

Tuning the LCST of poly(2-oxazoline)s by varying composition and molecular weight: alternatives to poly(N-isopropylacrylamide)?

Richard Hoogenboom ^{1, 2}

Hanneke M L Thijs ^{1, 2}

Mark J H C Jochems ¹

Bart M Van Lankvelt ¹

Martin W. M. Fijten ^{1, 2}

U. S. Schubert ^{1, 2, 3}

Hide authors affiliations Show authors affiliations: 3 affiliations

Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, P.O. Box 513, MB Eindhoven, The Netherlands |

Dutch Polymer Institute (DPI), P.O. Box 902, AX Eindhoven, The Netherlands |

Laboratory of Organic and Macromolecular Chemistry, Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, Jena, Germany |

Publication type: Journal Article

Publication date: 2008-10-02

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/b813140f

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PubMed ID: 19009072

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

The cloud point of copolymers of 2-ethyl-2-oxazoline and 2-n-propyl-2-oxazoline could be tuned from 25 degrees C to 100 degrees C by varying molecular weight and composition; the reversibility and concentration dependence of the cloud points were evaluated to assess the potential of these copoly(2-oxazoline)s as alternatives to poly(N-isopropylacrylamide).

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Graulus Geert-Jan

PhD in Chemistry, lecturer

23 publications, 799 citations

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Hoogenboom R. et al. Tuning the LCST of poly(2-oxazoline)s by varying composition and molecular weight: alternatives to poly(N-isopropylacrylamide)? // Chemical Communications. 2008. Vol. 44. p. 5758.

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Hoogenboom R., Thijs H. M. L., Jochems M. J. H. C., Van Lankvelt B. M., Fijten M. W. M., Schubert U. S. Tuning the LCST of poly(2-oxazoline)s by varying composition and molecular weight: alternatives to poly(N-isopropylacrylamide)? // Chemical Communications. 2008. Vol. 44. p. 5758.

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