Pyrazoles and pyrazolides—flexible synthons in self-assembly
Publication type: Journal Article
Publication date: 2009-01-23
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
DOI:
10.1039/b815577a
PubMed ID:
19274281
Inorganic Chemistry
Abstract
This Perspective summarises the chemistry of the pyrazole ring, and reviews the metal coordination modes adopted by 1H-pyrazoles and their anions. Pyrazolide anions are probably the most versatile ligands in coordination chemistry, with 20 different terminal or bridging coordination modes having been identified so far. Metal cluster compounds supported by pyrazolido ligation are surveyed, concentrating on those reported during the past ten years. Highlights include the wide structural diversity in apparently simple main group pyrazolides; luminescence and charge-transfer complexes in coinage metal pyrazolide clusters; the use of robust metal pyrazolide clusters to construct liquid crystals, supramolecular materials and metal-organic frameworks; and supramolecular complexes formed by pyrazolide-supported metallacrowns.
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308
Total citations:
308
Citations from 2025:
10
(3.25%)
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TY - JOUR
DO - 10.1039/b815577a
UR - https://doi.org/10.1039/b815577a
TI - Pyrazoles and pyrazolides—flexible synthons in self-assembly
T2 - Dalton Transactions
AU - Halcrow, Malcolm A.
PY - 2009
DA - 2009/01/23
PB - Royal Society of Chemistry (RSC)
SP - 2059
IS - 12
PMID - 19274281
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2009_Halcrow,
author = {Malcolm A. Halcrow},
title = {Pyrazoles and pyrazolides—flexible synthons in self-assembly},
journal = {Dalton Transactions},
year = {2009},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/b815577a},
number = {12},
pages = {2059},
doi = {10.1039/b815577a}
}