First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters
Publication type: Journal Article
Publication date: 2009-08-18
scimago Q1
wos Q1
SJR: 1.928
CiteScore: 16.1
Impact factor: 9.2
ISSN: 14639262, 14639270
DOI:
10.1039/b822924d
Environmental Chemistry
Pollution
Abstract
The modification of aliphatic polyesters by the copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) was successfully implemented in supercritical carbon dioxide (scCO2). Due to the remarkable properties of scCO2, the CuAAC reaction turned out to be quantitative even though the aliphatic polyesters used in this work were insoluble in scCO2 Interestingly enough, the conditions were mild enough to prevent polymer degradation from occurring and finally, efficient removal of the catalyst (>96%) was achieved by scCO2extraction.
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Total citations:
19
Citations from 2025:
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GOST
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Grignard B. et al. First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters // Green Chemistry. 2009. Vol. 11. No. 10. p. 1525.
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Grignard B., Schmeits S., Schmeits S., Riva R., Riva R., Detrembleur C., Lecomte P., Jérôme C. First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters // Green Chemistry. 2009. Vol. 11. No. 10. p. 1525.
Cite this
RIS
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TY - JOUR
DO - 10.1039/b822924d
UR - https://doi.org/10.1039/b822924d
TI - First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters
T2 - Green Chemistry
AU - Grignard, Bruno
AU - Schmeits, Stéphanie
AU - Schmeits, Stephanie
AU - Riva, Raphael
AU - Riva, Raphaël
AU - Detrembleur, Christophe
AU - Lecomte, P.
AU - Jérôme, Christine
PY - 2009
DA - 2009/08/18
PB - Royal Society of Chemistry (RSC)
SP - 1525
IS - 10
VL - 11
SN - 1463-9262
SN - 1463-9270
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Grignard,
author = {Bruno Grignard and Stéphanie Schmeits and Stephanie Schmeits and Raphael Riva and Raphaël Riva and Christophe Detrembleur and P. Lecomte and Christine Jérôme},
title = {First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters},
journal = {Green Chemistry},
year = {2009},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://doi.org/10.1039/b822924d},
number = {10},
pages = {1525},
doi = {10.1039/b822924d}
}
Cite this
MLA
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Grignard, Bruno, et al. “First example of “click” copper(i) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: application to the functionalization of aliphatic polyesters.” Green Chemistry, vol. 11, no. 10, Aug. 2009, p. 1525. https://doi.org/10.1039/b822924d.