Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes
Eduard Fron
1
,
E Coutino Gonzalez
1
,
Lesley Pandey
1
,
Michel Sliwa
2
,
Mark Van der Auweraer
1
,
Frans C. De Schryver
1
,
Joice Thomas
1
,
Zeyuan Dong
1
,
Volker Leen
1
,
Mario Smet
1
,
Wim Dehaen
1
,
Tom Vosch
1
Publication type: Journal Article
Publication date: 2009-04-14
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
DOI:
10.1039/b900786e
Materials Chemistry
General Chemistry
Catalysis
Abstract
Synthetic details and stationary and time-resolved photophysical properties of five BODIPY derivatives containing chalcogen atoms are presented. The photophysical data are compared to those of a chlorine atom containing BODIPY, acting as a reference. A strong impact in the HOMO–LUMO transition energy is achieved via nucleophilic substitution with chalcogen based units. Going from oxygen to tellurium a bathochromic shift in both absorption and emission spectra from the green to the near infrared region was observed. By employing fluorescence single photon timing experiments in two solvents of different polarity, the excited state dynamics and their solvent dependence indicate the presence of a mechanism involving a photoinduced charge transfer that dramatically affects the optical radiative processes of these derivatives.
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74
Total citations:
74
Citations from 2024:
7
(9.46%)
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Cite this
GOST
Copy
Fron E. et al. Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes // New Journal of Chemistry. 2009. Vol. 33. No. 7. p. 1490.
GOST all authors (up to 50)
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Fron E., Coutino Gonzalez E., Pandey L., Sliwa M., Auweraer M. V. D., De Schryver F. C., Thomas J., Dong Z., Leen V., Smet M., Dehaen W., Vosch T. Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes // New Journal of Chemistry. 2009. Vol. 33. No. 7. p. 1490.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/b900786e
UR - https://doi.org/10.1039/b900786e
TI - Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes
T2 - New Journal of Chemistry
AU - Fron, Eduard
AU - Coutino Gonzalez, E
AU - Pandey, Lesley
AU - Sliwa, Michel
AU - Auweraer, Mark Van der
AU - De Schryver, Frans C.
AU - Thomas, Joice
AU - Dong, Zeyuan
AU - Leen, Volker
AU - Smet, Mario
AU - Dehaen, Wim
AU - Vosch, Tom
PY - 2009
DA - 2009/04/14
PB - Royal Society of Chemistry (RSC)
SP - 1490
IS - 7
VL - 33
SN - 1144-0546
SN - 1369-9261
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Fron,
author = {Eduard Fron and E Coutino Gonzalez and Lesley Pandey and Michel Sliwa and Mark Van der Auweraer and Frans C. De Schryver and Joice Thomas and Zeyuan Dong and Volker Leen and Mario Smet and Wim Dehaen and Tom Vosch},
title = {Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes},
journal = {New Journal of Chemistry},
year = {2009},
volume = {33},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/b900786e},
number = {7},
pages = {1490},
doi = {10.1039/b900786e}
}
Cite this
MLA
Copy
Fron, Eduard, et al. “Synthesis and photophysical characterization of chalcogen substituted BODIPY dyes.” New Journal of Chemistry, vol. 33, no. 7, Apr. 2009, p. 1490. https://doi.org/10.1039/b900786e.
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