Analytical Methods, volume 2, issue 11, pages 1651

The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective

K. Grudpan ¹

Supaporn Kradtap Hartwell ¹

S LAPANANTNOPPAKHUN ¹

Ian McKelvie ²

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry and Center for Innovation in Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai, Thailand |

Water Studies Centre, School of Chemistry, Monash University, Victoria, Australia |

Publication type: Journal Article

Publication date: 2010-09-08

Royal Society of Chemistry (RSC)

Journal: Analytical Methods

Quartile SCImago

Quartile WOS

Impact factor: 3.1

ISSN: 17599660, 17599679

DOI: 10.1039/c0ay00253d

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General Chemical Engineering

Analytical Chemistry

General Engineering

Abstract

An important part of the Green Chemistry philosophy is the need to develop and adopt green analytical techniques and procedures. These include the reduction of reagent and solvent usage, the minimization of solid, liquid and gaseous materials produced by analytical processes, the replacement of reagents and solvents of high occupational or environmental toxicity with much more innocuous materials, and the reduction of energy use in analytical processes. One aspect that has received little attention in this context is the use of unrefined natural reagents derived from plant and animal tissues or microbial cells. Crude plant extracts may contain chemical compounds that enable their use as indicators in acid–base or redox titrations, or as chromogenic or fluorogenic agents. Enzymes extracted from plants may be used directly in soluble form, or incorporated in biosensors or solid phase reactors, for analytical measurements, or as a means of removing interferences or performing speciation studies. The use of natural reagents in conjunction with a flow injection system can confer a number of advantages. The enhanced kinetic control that flow analysis offers may assist in avoiding undesirable side reactions that would otherwise occur using unpurified reagents. The lifetime of natural reagents may be prolonged when used in a flow analysis system because their exposure to light or air can be controlled. Any changes in response that do occur may be readily corrected by regular standard checking and recalibration. This article reviews the use of natural reagents with an emphasis on flow-based analytical systems, and makes the case for further research in this latent area of green analytical chemistry.

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Citations by journals

	1 2 3 4 5
TrAC - Trends in Analytical Chemistry	TrAC - Trends in Analytical Chemistry, 5, 11.36% TrAC - Trends in Analytical Chemistry 5 publications, 11.36%
Talanta	Talanta, 4, 9.09% Talanta 4 publications, 9.09%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 3, 6.82% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 3 publications, 6.82%
Sustainability	Sustainability, 2, 4.55% Sustainability 2 publications, 4.55%
Analytical Sciences	Analytical Sciences, 2, 4.55% Analytical Sciences 2 publications, 4.55%
Microchemical Journal	Microchemical Journal, 2, 4.55% Microchemical Journal 2 publications, 4.55%
Journal of Chemical Education	Journal of Chemical Education, 2, 4.55% Journal of Chemical Education 2 publications, 4.55%
Journal of Water and Health	Journal of Water and Health, 1, 2.27% Journal of Water and Health 1 publication, 2.27%
Chromatographia	Chromatographia, 1, 2.27% Chromatographia 1 publication, 2.27%
Analytical and Bioanalytical Chemistry	Analytical and Bioanalytical Chemistry, 1, 2.27% Analytical and Bioanalytical Chemistry 1 publication, 2.27%
Advances in Sample Preparation	Advances in Sample Preparation, 1, 2.27% Advances in Sample Preparation 1 publication, 2.27%
Analytica Chimica Acta	Analytica Chimica Acta, 1, 2.27% Analytica Chimica Acta 1 publication, 2.27%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 1, 2.27% Sensors and Actuators, B: Chemical 1 publication, 2.27%
Current Opinion in Green and Sustainable Chemistry	Current Opinion in Green and Sustainable Chemistry, 1, 2.27% Current Opinion in Green and Sustainable Chemistry 1 publication, 2.27%
Sustainable Chemistry and Pharmacy	Sustainable Chemistry and Pharmacy, 1, 2.27% Sustainable Chemistry and Pharmacy 1 publication, 2.27%
Journal of Chromatography A	Journal of Chromatography A, 1, 2.27% Journal of Chromatography A 1 publication, 2.27%
ChemInform	ChemInform, 1, 2.27% ChemInform 1 publication, 2.27%
Chemistry Education Research and Practice	Chemistry Education Research and Practice, 1, 2.27% Chemistry Education Research and Practice 1 publication, 2.27%
Journal of Analytical Atomic Spectrometry	Journal of Analytical Atomic Spectrometry, 1, 2.27% Journal of Analytical Atomic Spectrometry 1 publication, 2.27%
Journal of Food and Drug Analysis	Journal of Food and Drug Analysis, 1, 2.27% Journal of Food and Drug Analysis 1 publication, 2.27%
International Journal of Environmental Analytical Chemistry	International Journal of Environmental Analytical Chemistry, 1, 2.27% International Journal of Environmental Analytical Chemistry 1 publication, 2.27%
Advances in Biological Chemistry	Advances in Biological Chemistry, 1, 2.27% Advances in Biological Chemistry 1 publication, 2.27%
Analytical Letters	Analytical Letters, 1, 2.27% Analytical Letters 1 publication, 2.27%
Journal of AOAC International	Journal of AOAC International, 1, 2.27% Journal of AOAC International 1 publication, 2.27%
Waste and Biomass Valorization	Waste and Biomass Valorization, 1, 2.27% Waste and Biomass Valorization 1 publication, 2.27%
Pure and Applied Chemistry	Pure and Applied Chemistry, 1, 2.27% Pure and Applied Chemistry 1 publication, 2.27%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 2.27% Russian Chemical Reviews 1 publication, 2.27%
Journal of Cleaner Production	Journal of Cleaner Production, 1, 2.27% Journal of Cleaner Production 1 publication, 2.27%
	1 2 3 4 5

Citations by publishers

	5 10 15 20 25
Elsevier	Elsevier, 22, 50% Elsevier 22 publications, 50%
Springer Nature	Springer Nature, 3, 6.82% Springer Nature 3 publications, 6.82%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 2, 4.55% Multidisciplinary Digital Publishing Institute (MDPI) 2 publications, 4.55%
Japan Society for Analytical Chemistry	Japan Society for Analytical Chemistry, 2, 4.55% Japan Society for Analytical Chemistry 2 publications, 4.55%
American Chemical Society (ACS)	American Chemical Society (ACS), 2, 4.55% American Chemical Society (ACS) 2 publications, 4.55%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 2, 4.55% Royal Society of Chemistry (RSC) 2 publications, 4.55%
Taylor & Francis	Taylor & Francis, 2, 4.55% Taylor & Francis 2 publications, 4.55%
IWA Publishing	IWA Publishing, 1, 2.27% IWA Publishing 1 publication, 2.27%
Wiley	Wiley, 1, 2.27% Wiley 1 publication, 2.27%
Scientific Research Publishing	Scientific Research Publishing, 1, 2.27% Scientific Research Publishing 1 publication, 2.27%
AOAC International	AOAC International, 1, 2.27% AOAC International 1 publication, 2.27%
Walter de Gruyter	Walter de Gruyter, 1, 2.27% Walter de Gruyter 1 publication, 2.27%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 2.27% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 2.27%
	5 10 15 20 25

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Grudpan K. et al. The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective // Analytical Methods. 2010. Vol. 2. No. 11. p. 1651.

GOST all authors (up to 50) Copy

Grudpan K., Hartwell S. K., LAPANANTNOPPAKHUN S., McKelvie I. The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective // Analytical Methods. 2010. Vol. 2. No. 11. p. 1651.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c0ay00253d

UR - https://doi.org/10.1039/c0ay00253d

TI - The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective

T2 - Analytical Methods

AU - Hartwell, Supaporn Kradtap

AU - McKelvie, Ian

AU - Grudpan, K.

AU - LAPANANTNOPPAKHUN, S

PY - 2010

DA - 2010/09/08 00:00:00

PB - Royal Society of Chemistry (RSC)

SP - 1651

IS - 11

VL - 2

SN - 1759-9660

SN - 1759-9679

ER -

BibTex |

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BibTex Copy

@article{2010_Grudpan,

author = {Supaporn Kradtap Hartwell and Ian McKelvie and K. Grudpan and S LAPANANTNOPPAKHUN},

title = {The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective},

journal = {Analytical Methods},

year = {2010},

volume = {2},

publisher = {Royal Society of Chemistry (RSC)},

month = {sep},

url = {https://doi.org/10.1039/c0ay00253d},

number = {11},

pages = {1651},

doi = {10.1039/c0ay00253d}

}

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Grudpan, K., et al. “The case for the use of unrefined natural reagents in analytical chemistry—A green chemical perspective.” Analytical Methods, vol. 2, no. 11, Sep. 2010, p. 1651. https://doi.org/10.1039/c0ay00253d.

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Royal Society of Chemistry (RSC)

Journal

Analytical Methods

Quartile SCImago

Quartile WOS

Impact factor

3.1

ISSN

17599660 (Print)
17599679 (Electronic)