Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions
Evgeni M Glebov
1, 2
,
Ivan P. Pozdnyakov
1, 2
,
Vjacheslav P Grivin
1, 2
,
Victor F. Plyusnin
1, 2
,
Xu Zhang
3
,
Feng Wu
3
,
Nansheng Deng
3
Publication type: Journal Article
Publication date: 2011-03-01
scimago Q2
wos Q2
SJR: 0.629
CiteScore: 5.1
Impact factor: 3.2
ISSN: 1474905X, 14749092
PubMed ID:
21031204
Physical and Theoretical Chemistry
Abstract
The primary processes in the photochemistry of Fe(III) complexes with carboxylic acids (glyoxalic, tartaric, pyruvic and lactic) were studied by means of laser flash photolysis. The inner-sphere electron transfer with the formation of Fe(II) complex and an escape of an organic radical to the solution bulk was shown to be a minor channel of the photolysis. The main channel was proposed to be the formation of a long-lived radical complex [FeII ... •OOC-R]2+. Spectral and kinetic parameters of the radical complexes are determined.
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Metrics
81
Total citations:
81
Citations from 2025:
7
(8.64%)
The most citing journal
Citations in journal:
9
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GOST
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Glebov E. M. et al. Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions // Photochemical and Photobiological Sciences. 2011. Vol. 10. No. 3. pp. 425-430.
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Glebov E. M., Pozdnyakov I. P., Grivin V. P., Plyusnin V. F., Zhang X., Wu F., Deng N. Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions // Photochemical and Photobiological Sciences. 2011. Vol. 10. No. 3. pp. 425-430.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c0pp00151a
UR - https://doi.org/10.1039/c0pp00151a
TI - Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions
T2 - Photochemical and Photobiological Sciences
AU - Glebov, Evgeni M
AU - Pozdnyakov, Ivan P.
AU - Grivin, Vjacheslav P
AU - Plyusnin, Victor F.
AU - Zhang, Xu
AU - Wu, Feng
AU - Deng, Nansheng
PY - 2011
DA - 2011/03/01
PB - Springer Nature
SP - 425-430
IS - 3
VL - 10
PMID - 21031204
SN - 1474-905X
SN - 1474-9092
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Glebov,
author = {Evgeni M Glebov and Ivan P. Pozdnyakov and Vjacheslav P Grivin and Victor F. Plyusnin and Xu Zhang and Feng Wu and Nansheng Deng},
title = {Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions},
journal = {Photochemical and Photobiological Sciences},
year = {2011},
volume = {10},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1039/c0pp00151a},
number = {3},
pages = {425--430},
doi = {10.1039/c0pp00151a}
}
Cite this
MLA
Copy
Glebov, Evgeni M., et al. “Intermediates in photochemistry of Fe(III) complexes with carboxylic acids in aqueous solutions.” Photochemical and Photobiological Sciences, vol. 10, no. 3, Mar. 2011, pp. 425-430. https://doi.org/10.1039/c0pp00151a.