Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems
Pablo Casuso
1
,
Pedro Carrasco
1
,
Iraida Loinaz
1
,
German Cabañero
1
,
Cabañero Germán
1
,
Hans J Grande
1
,
IBON ODRIOZOLA
1
1
CIDETEC, Centre for Electrochemical Technologies, New Materials Department, Paseo Miramón 196, Donostia-San Sebastián, Spain
|
Publication type: Journal Article
Publication date: 2011-02-17
scimago Q2
wos Q2
SJR: 0.684
CiteScore: 5.4
Impact factor: 2.8
ISSN: 1744683X, 17446848
General Chemistry
Condensed Matter Physics
Abstract
In this work we have studied the structure of silver(I) thiolate oligomers that lead to the formation of argentophilic hydrogels. The results showed two different and clearly distinguishable systems, depending on the neutral or acidic character of the thiol. Neutral systems gave opaque hydrogels, showed a fibrilar microstructure and were very dependent on the silver : thiol ratio. On the other hand, acidic hydrogels were transparent, showed a sheet-like microstructure and were not affected by the silver : thiol stoichiometry. The molecular weight of these metallophilic polymers was measured for the first time, to the best of our knowledge, by size-exclusion chromatography (SEC) and MALDI-TOF mass spectrometry. The results suggest that neutral hydrogels are composed of tetrameric species, whereas the acidic ones are composed of slightly longer oligomers (n = 8–14). In addition, several observations have shown the dynamic character of these oligomeric systems, opening the way for a novel and facile approach towards the fabrication of new multiresponsive soft materials.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
Soft Matter
5 publications, 15.15%
|
|
|
Coordination Chemistry Reviews
2 publications, 6.06%
|
|
|
ACS Nano
2 publications, 6.06%
|
|
|
Journal of Physical Chemistry C
2 publications, 6.06%
|
|
|
Chemical Communications
2 publications, 6.06%
|
|
|
Journal of Physics: Conference Series
1 publication, 3.03%
|
|
|
Materials Today Advances
1 publication, 3.03%
|
|
|
Journal of Colloid and Interface Science
1 publication, 3.03%
|
|
|
Colloids and Surfaces A: Physicochemical and Engineering Aspects
1 publication, 3.03%
|
|
|
Journal of Polymer Science, Part A: Polymer Chemistry
1 publication, 3.03%
|
|
|
Chemistry - A European Journal
1 publication, 3.03%
|
|
|
Angewandte Chemie - International Edition
1 publication, 3.03%
|
|
|
Angewandte Chemie
1 publication, 3.03%
|
|
|
Small
1 publication, 3.03%
|
|
|
Advanced Materials
1 publication, 3.03%
|
|
|
Chemical Reviews
1 publication, 3.03%
|
|
|
Langmuir
1 publication, 3.03%
|
|
|
ACS applied materials & interfaces
1 publication, 3.03%
|
|
|
Biomacromolecules
1 publication, 3.03%
|
|
|
ACS Applied Nano Materials
1 publication, 3.03%
|
|
|
Organic and Biomolecular Chemistry
1 publication, 3.03%
|
|
|
CrystEngComm
1 publication, 3.03%
|
|
|
Mendeleev Communications
1 publication, 3.03%
|
|
|
Gels
1 publication, 3.03%
|
|
|
Inorganic Chemistry
1 publication, 3.03%
|
|
|
1
2
3
4
5
|
Publishers
|
2
4
6
8
10
|
|
|
American Chemical Society (ACS)
10 publications, 30.3%
|
|
|
Royal Society of Chemistry (RSC)
9 publications, 27.27%
|
|
|
Wiley
6 publications, 18.18%
|
|
|
Elsevier
5 publications, 15.15%
|
|
|
IOP Publishing
1 publication, 3.03%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 3.03%
|
|
|
MDPI
1 publication, 3.03%
|
|
|
2
4
6
8
10
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
33
Total citations:
33
Citations from 2025:
1
(3.03%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Casuso P. et al. Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems // Soft Matter. 2011. Vol. 7. No. 7. p. 3627.
GOST all authors (up to 50)
Copy
Casuso P., Carrasco P., Loinaz I., Cabañero G., Germán C., Grande H. J., ODRIOZOLA I. Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems // Soft Matter. 2011. Vol. 7. No. 7. p. 3627.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c0sm01217c
UR - https://doi.org/10.1039/c0sm01217c
TI - Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems
T2 - Soft Matter
AU - Casuso, Pablo
AU - Carrasco, Pedro
AU - Loinaz, Iraida
AU - Cabañero, German
AU - Germán, Cabañero
AU - Grande, Hans J
AU - ODRIOZOLA, IBON
PY - 2011
DA - 2011/02/17
PB - Royal Society of Chemistry (RSC)
SP - 3627
IS - 7
VL - 7
SN - 1744-683X
SN - 1744-6848
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Casuso,
author = {Pablo Casuso and Pedro Carrasco and Iraida Loinaz and German Cabañero and Cabañero Germán and Hans J Grande and IBON ODRIOZOLA},
title = {Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems},
journal = {Soft Matter},
year = {2011},
volume = {7},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/c0sm01217c},
number = {7},
pages = {3627},
doi = {10.1039/c0sm01217c}
}
Cite this
MLA
Copy
Casuso, Pablo, et al. “Argentophilic hydrogels: elucidating the structure of neutral versus acidic systems.” Soft Matter, vol. 7, no. 7, Feb. 2011, p. 3627. https://doi.org/10.1039/c0sm01217c.