Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts
Adriana Bonilla Sánchez
1, 2
,
Narcís Homs
1, 2
,
Sylvain Miachon
3
,
Jean-Alain Dalmon
3
,
Jose Luis Garcia Fierro
4
,
Pilar Ramirez de la Piscina
1
1
Publication type: Journal Article
Publication date: 2011-07-28
scimago Q1
wos Q1
SJR: 1.928
CiteScore: 16.1
Impact factor: 9.2
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
Ethanol dehydrogenating coupling was studied at 523 K and 1 MPa over catalytic membrane reactors (CMRs) and conventional supported catalysts based on Pd or Pd-Zn on CeO2-ZrO2. A wet impregnation method based on evaporation-crystallization was used to deposit Pd or Pd and Zn on membrane reactors of TiO2 with a top layer of CeO2-ZrO2 and a pore size of 5 nm. These systems were compared with conventional CeO2-ZrO2-supported Pd or Pd-Zn catalysts. Monometallic Pd systems favoured the decomposition of ethanol giving CO and CH4 as the main products. The presence of Zn in both Pd/CeO2-ZrO2 and CMRs containing Pd inhibited ethanol decomposition and favoured the production of acetaldehyde; the effect is greater for CMRs and is related to the presence of PdZn entities together with the porous system of CMRs. Acetaldehyde was subsequently transformed to ethyl acetate.
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18
Total citations:
18
Citations from 2025:
2
(11.11%)
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GOST
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Sánchez A. B. et al. Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts // Green Chemistry. 2011. Vol. 13. No. 9. p. 2569.
GOST all authors (up to 50)
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Sánchez A. B., Homs N., Miachon S., Dalmon J., Garcia Fierro J. L., Ramirez de la Piscina P. Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts // Green Chemistry. 2011. Vol. 13. No. 9. p. 2569.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c1gc15559h
UR - https://doi.org/10.1039/c1gc15559h
TI - Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts
T2 - Green Chemistry
AU - Sánchez, Adriana Bonilla
AU - Homs, Narcís
AU - Miachon, Sylvain
AU - Dalmon, Jean-Alain
AU - Garcia Fierro, Jose Luis
AU - Ramirez de la Piscina, Pilar
PY - 2011
DA - 2011/07/28
PB - Royal Society of Chemistry (RSC)
SP - 2569
IS - 9
VL - 13
SN - 1463-9262
SN - 1463-9270
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Sánchez,
author = {Adriana Bonilla Sánchez and Narcís Homs and Sylvain Miachon and Jean-Alain Dalmon and Jose Luis Garcia Fierro and Pilar Ramirez de la Piscina},
title = {Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts},
journal = {Green Chemistry},
year = {2011},
volume = {13},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://doi.org/10.1039/c1gc15559h},
number = {9},
pages = {2569},
doi = {10.1039/c1gc15559h}
}
Cite this
MLA
Copy
Sánchez, Adriana Bonilla, et al. “Direct transformation of ethanol into ethyl acetate through catalytic membranes containing Pd or Pd-Zn: comparison with conventional supported catalysts.” Green Chemistry, vol. 13, no. 9, Jul. 2011, p. 2569. https://doi.org/10.1039/c1gc15559h.