Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism
Publication type: Journal Article
Publication date: 2012-01-01
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
22299129
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A detailed study on the scope of the efficient PtCl(2)-catalyzed synthesis of carbazoles from 1-(indol-2-yl)-2,3-allenols is described. Through isotopic labeling experiments, it is confirmed that the reaction proceeds through a unique metal carbene intermediate, which undergoes subsequent highly selective 1,2-hydrogen migration to afford carbazoles. The reaction shows wide scope and allows the introduction of a variety of different substituents at different positions on the carbazole due to the substituent-loading capability of both indole and the allene moiety.
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47
Total citations:
47
Citations from 2024:
2
(4.26%)
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GOST
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Kong W., FU C., Ma S. Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 10. p. 2164.
GOST all authors (up to 50)
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Kong W., FU C., Ma S. Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism // Organic and Biomolecular Chemistry. 2012. Vol. 10. No. 10. p. 2164.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c1ob06474f
UR - https://doi.org/10.1039/c1ob06474f
TI - Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism
T2 - Organic and Biomolecular Chemistry
AU - Kong, Wangqing
AU - FU, CHUNLING
AU - Ma, Sheng-Ming
PY - 2012
DA - 2012/01/01
PB - Royal Society of Chemistry (RSC)
SP - 2164
IS - 10
VL - 10
PMID - 22299129
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2012_Kong,
author = {Wangqing Kong and CHUNLING FU and Sheng-Ming Ma},
title = {Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism},
journal = {Organic and Biomolecular Chemistry},
year = {2012},
volume = {10},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c1ob06474f},
number = {10},
pages = {2164},
doi = {10.1039/c1ob06474f}
}
Cite this
MLA
Copy
Kong, Wangqing, et al. “Efficient synthesis of carbazoles via PtCl2-catalyzed RT cyclization of 1-(indol-2-yl)-2,3-allenols: scope and mechanism.” Organic and Biomolecular Chemistry, vol. 10, no. 10, Jan. 2012, p. 2164. https://doi.org/10.1039/c1ob06474f.
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