Journal of the Chemical Society Chemical Communications

, issue 21 , pages 1596

A simple synthesis of [NS]+[AlCl4]? and the insertion reaction with alkylselenium halides: X-ray structure of [N2S2SeCl]+[AlCl4]?

A. W. Apblett

Tristram Chivers

James F. Fait

Publication type: Journal Article

Publication date: 1989-01-01

Royal Society of Chemistry (RSC)

Journal of the Chemical Society Chemical Communications

SJR: —

CiteScore: —

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ISSN: 00224936

DOI: 10.1039/c39890001596

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Molecular Medicine

Abstract

The reaction of (NSCl)3 with aluminium trichloride at 50 °C without solvent, preferably with ultrasonic irradiation, produces [NS]+[AlCl4]– in good yields; the thiazyl salt reacts with alkylselenium halides to give [N2S2SeCl]+[AlCl4]–, in which the cation is shown by X-ray crystallography to be a five-membered ring with chlorine attached to selenium.

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Apblett A. W., Chivers T., Fait J. F. A simple synthesis of [NS]+[AlCl4]? and the insertion reaction with alkylselenium halides: X-ray structure of [N2S2SeCl]+[AlCl4]? // Journal of the Chemical Society Chemical Communications. 1989. Vol. 21. p. 1596.

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