Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2
Andrei V. Shlyahtin
1, 2, 3
,
Ilya E. Nifant'ev
1, 2, 3, 4
,
Vladimir V Bagrov
1
,
Dmitrii A. Lemenovskii
1, 2
,
Aleksander N Tavtorkin
3, 4
,
3
ELBRUS Scientific Technical Center, Moscow, Russia
|
Publication type: Journal Article
Publication date: 2014-01-01
scimago Q1
wos Q1
SJR: 1.928
CiteScore: 16.1
Impact factor: 9.2
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
Binary and ternary acrylonitrile (AN) copolymers with methyl acrylate (MA) and either itaconic acid (IA, 1) or IA derivatives (monomethyl itaconate (2), monoethyl itaconate (3), IA monoamide (4), IA mono-n-octylamide (5)) were prepared in CO2. The obtained copolymers have good morphological and molecular weight characteristics. They demonstrate broad heat evolution during thermal cyclisation according to DSC measurements; therefore, they may be used to produce carbon fibres. The polymer yield per reaction volume is 2 to 3 times higher relative to that produced in solution (in DMSO or DMF) or an aqueous suspension.
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Metrics
27
Total citations:
27
Citations from 2024:
5
(18%)
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GOST
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Shlyahtin A. V. et al. Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2 // Green Chemistry. 2014. Vol. 16. No. 3. pp. 1344-1350.
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Shlyahtin A. V., Nifant'ev I. E., Bagrov V. V., Lemenovskii D. A., Tavtorkin A. N., Timashev P. S. Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2 // Green Chemistry. 2014. Vol. 16. No. 3. pp. 1344-1350.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c3gc41677a
UR - https://xlink.rsc.org/?DOI=C3GC41677A
TI - Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2
T2 - Green Chemistry
AU - Shlyahtin, Andrei V.
AU - Nifant'ev, Ilya E.
AU - Bagrov, Vladimir V
AU - Lemenovskii, Dmitrii A.
AU - Tavtorkin, Aleksander N
AU - Timashev, Petr S.
PY - 2014
DA - 2014/01/01
PB - Royal Society of Chemistry (RSC)
SP - 1344-1350
IS - 3
VL - 16
SN - 1463-9262
SN - 1463-9270
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Shlyahtin,
author = {Andrei V. Shlyahtin and Ilya E. Nifant'ev and Vladimir V Bagrov and Dmitrii A. Lemenovskii and Aleksander N Tavtorkin and Petr S. Timashev},
title = {Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2},
journal = {Green Chemistry},
year = {2014},
volume = {16},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C3GC41677A},
number = {3},
pages = {1344--1350},
doi = {10.1039/c3gc41677a}
}
Cite this
MLA
Copy
Shlyahtin, Andrei V., et al. “Synthesis of polyacrylonitrile copolymers as potential carbon fibre precursors in CO2.” Green Chemistry, vol. 16, no. 3, Jan. 2014, pp. 1344-1350. https://xlink.rsc.org/?DOI=C3GC41677A.