Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes
1
Danish National Research Foundation, Center for DNA Nanotechnology, Department of Chemistry and iNANO, Gustav Wieds Vej 14, 8000 Aarhus C, Denmark
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Publication type: Journal Article
Publication date: 2013-09-19
scimago Q2
wos Q2
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
24132123
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
Fluoride detection through hydrogen bonding or deprotonation is most commonly achieved using amide, urea or pyrrole derivatives. The sensor molecules are often complex constructs and several synthetic steps are required for their preparation. Here we report the discovery that simple arylaldoximes have remarkable properties as fluoride anion sensors, providing distinct colorimetric or fluorescent readouts, depending on the structure of the arylaldoxime. The oximes showed exceptional selectivity towards fluoride over other typical anions, and low detection limits for fluoride in both DMSO and DMSO-water mixtures were obtained.
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Rosen C. B., Hansen D. J., Gothelf K. V. Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes // Organic and Biomolecular Chemistry. 2013. Vol. 11. No. 45. p. 7916.
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Rosen C. B., Hansen D. J., Gothelf K. V. Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes // Organic and Biomolecular Chemistry. 2013. Vol. 11. No. 45. p. 7916.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c3ob41078a
UR - https://doi.org/10.1039/c3ob41078a
TI - Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes
T2 - Organic and Biomolecular Chemistry
AU - Rosen, Christian B
AU - Hansen, Dennis J
AU - Gothelf, Kurt V.
PY - 2013
DA - 2013/09/19
PB - Royal Society of Chemistry (RSC)
SP - 7916
IS - 45
VL - 11
PMID - 24132123
SN - 1477-0520
SN - 1477-0539
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Rosen,
author = {Christian B Rosen and Dennis J Hansen and Kurt V. Gothelf},
title = {Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes},
journal = {Organic and Biomolecular Chemistry},
year = {2013},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://doi.org/10.1039/c3ob41078a},
number = {45},
pages = {7916},
doi = {10.1039/c3ob41078a}
}
Cite this
MLA
Copy
Rosen, Christian B., et al. “Efficient colorimetric and fluorescent detection of fluoride in DMSO–water mixtures with arylaldoximes.” Organic and Biomolecular Chemistry, vol. 11, no. 45, Sep. 2013, p. 7916. https://doi.org/10.1039/c3ob41078a.