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Open access
Royal Society of Chemistry (RSC)
RSC Advances
,  volume 4 ,  issue 20 ,  pages 10228-10239

Metal binding properties of pyrimidinophanes and their acyclic counterparts

Publication type: Journal Article
Publication date: 2014-01-30
Royal Society of Chemistry (RSC)
scimago Q1
wos Q2
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
General Chemistry
General Chemical Engineering
Abstract
A series of acyclic and macrocyclic nucleobase derivatives that contain uracil and 2-thiocytosine units linked by polymethylene spacers was prepared. The length of spacers as well as the oxidation number of sulfur atoms entering into the structure of the compounds was varied. The crystal structure of pyrimidinophane with hexa- and heptamethylene linkers was established by X-ray analysis. The metal ion-binding properties of pyrimidinophanes and their acyclic counterparts were investigated by liquid extraction and 1H NMR titration experiments. The compounds with 2-thiocytosine fragments revealed a high selectivity of extraction towards Ag+ ions. The stoichiometry of silver complexes and the binding constants have been determined. The antibacterial activity of these complexes was also discussed.
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GOST |
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GOST Copy
Podyachev S. N. et al. Metal binding properties of pyrimidinophanes and their acyclic counterparts // RSC Advances. 2014. Vol. 4. No. 20. pp. 10228-10239.
GOST all authors (up to 50) Copy
Podyachev S. N., Semenov V., Syakaev V. V., Kashapova N. E., Sudakova S. N., Voronina J. K., Mikhailov A. S., Voloshina A. D., Reznik V., Konovalov A. N. Metal binding properties of pyrimidinophanes and their acyclic counterparts // RSC Advances. 2014. Vol. 4. No. 20. pp. 10228-10239.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/c3ra47571a
UR - https://doi.org/10.1039/c3ra47571a
TI - Metal binding properties of pyrimidinophanes and their acyclic counterparts
T2 - RSC Advances
AU - Podyachev, Sergey N.
AU - Semenov, Vyacheslav
AU - Syakaev, Victor V.
AU - Kashapova, Nadezda E
AU - Sudakova, Svetlana N.
AU - Voronina, Julia K.
AU - Mikhailov, Anatoly S
AU - Voloshina, A. D.
AU - Reznik, Vladimir S.
AU - Konovalov, Alexander N.
PY - 2014
DA - 2014/01/30
PB - Royal Society of Chemistry (RSC)
SP - 10228-10239
IS - 20
VL - 4
SN - 2046-2069
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2014_Podyachev,
author = {Sergey N. Podyachev and Vyacheslav Semenov and Victor V. Syakaev and Nadezda E Kashapova and Svetlana N. Sudakova and Julia K. Voronina and Anatoly S Mikhailov and A. D. Voloshina and Vladimir S. Reznik and Alexander N. Konovalov},
title = {Metal binding properties of pyrimidinophanes and their acyclic counterparts},
journal = {RSC Advances},
year = {2014},
volume = {4},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c3ra47571a},
number = {20},
pages = {10228--10239},
doi = {10.1039/c3ra47571a}
}
MLA
Cite this
MLA Copy
Podyachev, Sergey N., et al. “Metal binding properties of pyrimidinophanes and their acyclic counterparts.” RSC Advances, vol. 4, no. 20, Jan. 2014, pp. 10228-10239. https://doi.org/10.1039/c3ra47571a.