An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites
1
National Energy Technology Laboratory, United States Department of Energy, P. O. Box 10940, Pittsburgh, PA 15236, USA
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Publication type: Journal Article
Publication date: 2014-01-08
scimago Q1
wos Q1
SJR: 2.462
CiteScore: 16.7
Impact factor: 9.5
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
One interesting class of materials for oxygen storage applications are double perovskite oxides due to their ability to rapidly store and release oxygen. Previously, the double perovskite BaYMn2O5+δ was shown to rapidly and reversibly store and release oxygen with unprecedented kinetics. In this work, four double perovskite materials, BaLaFe2O5+δ, BaLaCo2O5+δ, BaYCo2O5+δ, and BaYFe2O5+δ, were synthesized and characterized. TGA experimental results for all four samples demonstrate rapid and reversible oxygen storage. The two Fe-containing compounds are the most stable for multiple adsorption/desorption cycles with both nitrogen/air and hydrogen/air at multiple temperatures and have been demonstrated to oxidize methane.
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Total citations:
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Citations from 2024:
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(25%)
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Lekse J. W. et al. An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites // Journal of Materials Chemistry A. 2014. Vol. 2. No. 7. p. 2397.
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Lekse J. W., Natesakhawat S., Alfonso D., Matranga C. An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites // Journal of Materials Chemistry A. 2014. Vol. 2. No. 7. p. 2397.
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RIS
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TY - JOUR
DO - 10.1039/c3ta13257a
UR - https://doi.org/10.1039/c3ta13257a
TI - An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites
T2 - Journal of Materials Chemistry A
AU - Lekse, Jonathan W
AU - Natesakhawat, Sittichai
AU - Alfonso, Dominic
AU - Matranga, Christopher
PY - 2014
DA - 2014/01/08
PB - Royal Society of Chemistry (RSC)
SP - 2397
IS - 7
VL - 2
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
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BibTex (up to 50 authors)
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@article{2014_Lekse,
author = {Jonathan W Lekse and Sittichai Natesakhawat and Dominic Alfonso and Christopher Matranga},
title = {An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites},
journal = {Journal of Materials Chemistry A},
year = {2014},
volume = {2},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://doi.org/10.1039/c3ta13257a},
number = {7},
pages = {2397},
doi = {10.1039/c3ta13257a}
}
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MLA
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Lekse, Jonathan W., et al. “An experimental and computational investigation of the oxygen storage properties of BaLnFe2O5+δ and BaLnCo2O5+δ (Ln = La, Y) perovskites.” Journal of Materials Chemistry A, vol. 2, no. 7, Jan. 2014, p. 2397. https://doi.org/10.1039/c3ta13257a.