Chemical Communications, volume 50, issue 50, pages 6633

A cobalt(ii) bis(salicylate)-based ionic liquid that shows thermoresponsive and selective water coordination

Yuki Kohno ¹

Matthew Cowan ¹

Miyuki Masuda ²

Indrani Bhowmick ³

Matthew W. Shores ³

Douglas Gin ^{1, 4}

Richard W. Noble ¹

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Dept. of Chemical & Biological Engineering, University of Colorado, Boulder, USA |

Dept. of Biotechnology and Life Science, Tokyo University of Agriculture and Technology, 2-24-16, Naka-cho, Koganei, Tokyo 184-8588, Japan |

Dept. of Chemistry, Colorado State University, Fort Collins, USA |

⁴

Dept. of Chemistry & Biochemistry, University of Colorado, Boulder, USA |

Publication type: Journal Article

Publication date: 2014-05-13

Royal Society of Chemistry (RSC)

Journal: Chemical Communications

scimago Q1

SJR: 1.133

CiteScore: 8.6

Impact factor: 4.3

ISSN: 13597345, 1364548X

DOI: 10.1039/c4cc01023j

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PubMed ID: 24824879

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

A metal-containing ionic liquid (MCIL) has been prepared in which the [Co(II)(salicylate)2](2-) anion is able to selectively coordinate two water molecules with a visible colour change, even in the presence of alcohols. Upon moderate heating or placement in vacuo, the hydrated MCIL undergoes reversible thermochromism by releasing the bound water molecules.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

SJR

1.133

CiteScore

8.6

Impact factor

4.3

ISSN

13597345 (Print)

1364548X (Electronic)

A cobalt(ii) bis(salicylate)-based ionic liquid that shows thermoresponsive and selective water coordination

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