Open Access
Carborane polyimides, synthesis and characterization
1
Institute of System and Engineering, Chinese Academy of Engineering Physics, Mianyang 621900, China
|
Publication type: Journal Article
Publication date: 2014-10-08
scimago Q1
wos Q2
SJR: 0.777
CiteScore: 7.6
Impact factor: 4.6
ISSN: 20462069
General Chemistry
General Chemical Engineering
Abstract
Here we report the syntheses of polyimides with meta-carborane cages embedded in the polymer chain and their characterizations. Aromatic carborane diamines were prepared by a Sonogashira reaction in the first place; reaction of the obtained diamines with commercially available dianhydride led to the formation of carborane polyimides with high molecular weight. Thermogravimetric analysis (TGA) of the samples showed that they have excellent thermal stability, with 5 wt% decomposition temperatures (Td5%) higher than 520 °C. Due to the boron-rich nature of the obtained polyimides, samples prepared here have potential applications in the aerospace industry and nuclear power stations as building blocks for neutron shielding and detecting devices.
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Metrics
29
Total citations:
29
Citations from 2025:
5
(17.24%)
Cite this
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BibTex |
MLA
Cite this
GOST
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Xing T. et al. Carborane polyimides, synthesis and characterization // RSC Advances. 2014. Vol. 4. No. 96. pp. 53628-53633.
GOST all authors (up to 50)
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Xing T., Huang Y., Zhang K., Wu J. Carborane polyimides, synthesis and characterization // RSC Advances. 2014. Vol. 4. No. 96. pp. 53628-53633.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c4ra09886b
UR - https://doi.org/10.1039/c4ra09886b
TI - Carborane polyimides, synthesis and characterization
T2 - RSC Advances
AU - Xing, Tao
AU - Huang, Yuhong
AU - Zhang, Kai
AU - Wu, Juying
PY - 2014
DA - 2014/10/08
PB - Royal Society of Chemistry (RSC)
SP - 53628-53633
IS - 96
VL - 4
SN - 2046-2069
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Xing,
author = {Tao Xing and Yuhong Huang and Kai Zhang and Juying Wu},
title = {Carborane polyimides, synthesis and characterization},
journal = {RSC Advances},
year = {2014},
volume = {4},
publisher = {Royal Society of Chemistry (RSC)},
month = {oct},
url = {https://doi.org/10.1039/c4ra09886b},
number = {96},
pages = {53628--53633},
doi = {10.1039/c4ra09886b}
}
Cite this
MLA
Copy
Xing, Tao, et al. “Carborane polyimides, synthesis and characterization.” RSC Advances, vol. 4, no. 96, Oct. 2014, pp. 53628-53633. https://doi.org/10.1039/c4ra09886b.