Physical Chemistry Chemical Physics, volume 17, issue 19, pages 12466-12471
Nonstoichiometry of nanocrystalline monoclinic silver sulfide
Publication type: Journal Article
Publication date: 2015-04-28
Journal:
Physical Chemistry Chemical Physics
Q2
Q1
SJR: 0.721
CiteScore: 5.5
Impact factor: 2.9
ISSN: 14639076, 14639084
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Powders of silver sulfide have been synthesized by chemical bath deposition from aqueous solutions of silver nitrate and sodium sulfide in the presence of sodium citrate or EDTA-H2Na2. Colloid solutions have been prepared by a chemical condensation method from the same aqueous solutions. Synthesized silver sulfide nanopowders have a monoclinic (space group P21/c) acanthite-type structure but the occupancy of the metal sublattice sites by Ag atoms is smaller than 1. Unlike coarse-crystalline silver sulfide Ag2S, silver sulfide nanopowders with particles sizes of less than ∼50 nm are nonstoichiometric, contain vacant sites in the metal sublattice and have a composition of ∼Ag1.93S.
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Sadovnikov S. I. et al. Nonstoichiometry of nanocrystalline monoclinic silver sulfide // Physical Chemistry Chemical Physics. 2015. Vol. 17. No. 19. pp. 12466-12471.
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Sadovnikov S. I., Gusev A. I., Rempel A. Nonstoichiometry of nanocrystalline monoclinic silver sulfide // Physical Chemistry Chemical Physics. 2015. Vol. 17. No. 19. pp. 12466-12471.
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RIS
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TY - JOUR
DO - 10.1039/c5cp00650c
UR - https://doi.org/10.1039/c5cp00650c
TI - Nonstoichiometry of nanocrystalline monoclinic silver sulfide
T2 - Physical Chemistry Chemical Physics
AU - Sadovnikov, Stanislav I
AU - Gusev, Aleksandr I.
AU - Rempel, Andrey
PY - 2015
DA - 2015/04/28
PB - Royal Society of Chemistry (RSC)
SP - 12466-12471
IS - 19
VL - 17
SN - 1463-9076
SN - 1463-9084
ER -
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@article{2015_Sadovnikov,
author = {Stanislav I Sadovnikov and Aleksandr I. Gusev and Andrey Rempel},
title = {Nonstoichiometry of nanocrystalline monoclinic silver sulfide},
journal = {Physical Chemistry Chemical Physics},
year = {2015},
volume = {17},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/c5cp00650c},
number = {19},
pages = {12466--12471},
doi = {10.1039/c5cp00650c}
}
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MLA
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Sadovnikov, Stanislav I., et al. “Nonstoichiometry of nanocrystalline monoclinic silver sulfide.” Physical Chemistry Chemical Physics, vol. 17, no. 19, Apr. 2015, pp. 12466-12471. https://doi.org/10.1039/c5cp00650c.
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