Nonstoichiometry of nanocrystalline monoclinic silver sulfide
Publication type: Journal Article
Publication date: 2015-04-28
scimago Q2
wos Q2
SJR: 0.698
CiteScore: 5.3
Impact factor: 2.9
ISSN: 14639076, 14639084
PubMed ID:
25917058
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Powders of silver sulfide have been synthesized by chemical bath deposition from aqueous solutions of silver nitrate and sodium sulfide in the presence of sodium citrate or EDTA-H2Na2. Colloid solutions have been prepared by a chemical condensation method from the same aqueous solutions. Synthesized silver sulfide nanopowders have a monoclinic (space group P21/c) acanthite-type structure but the occupancy of the metal sublattice sites by Ag atoms is smaller than 1. Unlike coarse-crystalline silver sulfide Ag2S, silver sulfide nanopowders with particles sizes of less than ∼50 nm are nonstoichiometric, contain vacant sites in the metal sublattice and have a composition of ∼Ag1.93S.
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91
Total citations:
91
Citations from 2024:
9
(9.89%)
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GOST
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Sadovnikov S. I. et al. Nonstoichiometry of nanocrystalline monoclinic silver sulfide // Physical Chemistry Chemical Physics. 2015. Vol. 17. No. 19. pp. 12466-12471.
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Sadovnikov S. I., Gusev A. I., Rempel A. Nonstoichiometry of nanocrystalline monoclinic silver sulfide // Physical Chemistry Chemical Physics. 2015. Vol. 17. No. 19. pp. 12466-12471.
Cite this
RIS
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TY - JOUR
DO - 10.1039/c5cp00650c
UR - https://doi.org/10.1039/c5cp00650c
TI - Nonstoichiometry of nanocrystalline monoclinic silver sulfide
T2 - Physical Chemistry Chemical Physics
AU - Sadovnikov, Stanislav I
AU - Gusev, Aleksandr I.
AU - Rempel, Andrey
PY - 2015
DA - 2015/04/28
PB - Royal Society of Chemistry (RSC)
SP - 12466-12471
IS - 19
VL - 17
PMID - 25917058
SN - 1463-9076
SN - 1463-9084
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Sadovnikov,
author = {Stanislav I Sadovnikov and Aleksandr I. Gusev and Andrey Rempel},
title = {Nonstoichiometry of nanocrystalline monoclinic silver sulfide},
journal = {Physical Chemistry Chemical Physics},
year = {2015},
volume = {17},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://doi.org/10.1039/c5cp00650c},
number = {19},
pages = {12466--12471},
doi = {10.1039/c5cp00650c}
}
Cite this
MLA
Copy
Sadovnikov, Stanislav I., et al. “Nonstoichiometry of nanocrystalline monoclinic silver sulfide.” Physical Chemistry Chemical Physics, vol. 17, no. 19, Apr. 2015, pp. 12466-12471. https://doi.org/10.1039/c5cp00650c.
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