Chemical Communications

, том 52 , издание 88 , страницы 12960-12963

Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Andrea Monas ¹

K. Užarević ¹

Ivan Halasz ¹

Monika Kulcsar ¹

Manda Ćurić ¹

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Division of Physical Chemistry, Ruđer Bošković Institute, Bijenička 54, HR-10000 Zagreb, Croatia |

Тип публикации: Journal Article

Дата публикации: 2016-09-01

Royal Society of Chemistry (RSC)

Chemical Communications

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SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/c6cc06062e

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PubMed ID: 27711274

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Краткое описание

Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C-H bonds of azobenzene and methyl orange by palladium(ii) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.

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Monas A. et al. Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor // Chemical Communications. 2016. Vol. 52. No. 88. pp. 12960-12963.

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Monas A., Užarević K., Halasz I., Kulcsar M., Ćurić M. Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor // Chemical Communications. 2016. Vol. 52. No. 88. pp. 12960-12963.

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TY - JOUR

DO - 10.1039/c6cc06062e

UR - https://doi.org/10.1039/c6cc06062e

TI - Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

T2 - Chemical Communications

AU - Monas, Andrea

AU - Užarević, K.

AU - Halasz, Ivan

AU - Kulcsar, Monika

AU - Ćurić, Manda

PY - 2016

DA - 2016/09/01

PB - Royal Society of Chemistry (RSC)

SP - 12960-12963

IS - 88

VL - 52

PMID - 27711274

SN - 1359-7345

SN - 1364-548X

ER -

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@article{2016_Monas,

author = {Andrea Monas and K. Užarević and Ivan Halasz and Monika Kulcsar and Manda Ćurić},

title = {Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor},

journal = {Chemical Communications},

year = {2016},

volume = {52},

publisher = {Royal Society of Chemistry (RSC)},

month = {sep},

url = {https://doi.org/10.1039/c6cc06062e},

number = {88},

pages = {12960--12963},

doi = {10.1039/c6cc06062e}

}

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Monas, Andrea, et al. “Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor.” Chemical Communications, vol. 52, no. 88, Sep. 2016, pp. 12960-12963. https://doi.org/10.1039/c6cc06062e.