Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal
Тип публикации: Journal Article
Дата публикации: 2016-09-12
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SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
This work is devoted to the complex research on temperature phase transitions in a CsScF4 crystal. The crystal structure was solved and refined at different temperatures by using the Rietveld method. Structural phase transitions were investigated by using the following spectroscopic methods, some of them for the first time: Brillouin spectroscopy, Raman spectroscopy, IR absorption spectroscopy and NMR. The symmetry analysis of the Brillouin zone center of all phases is presented. The vibrational spectra of the crystal in three phases have been calculated. The structural phase transition mechanism was determined. The transitions at T1 = 475 K and T2 = 317.5 K are of displacement type. The Raman soft modes have been associated with rotations of the ScF6 octahedral group.
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Krylov A. A. et al. Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal // CrystEngComm. 2016. Vol. 18. No. 43. pp. 8472-8486.
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Krylov A. A., Molokeev M. S., Misyul S. V., Krylova S. N., Oreshonkov A. S., Ivanenko A. A., Zykova V. A., Ivanov Y. N., Sukhovsky A. A., Voronov V. N., Safonov I. N., Vtyurin A. N. Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal // CrystEngComm. 2016. Vol. 18. No. 43. pp. 8472-8486.
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TY - JOUR
DO - 10.1039/c6ce01144f
UR - https://xlink.rsc.org/?DOI=C6CE01144F
TI - Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal
T2 - CrystEngComm
AU - Krylov, A. A.
AU - Molokeev, Maxim S.
AU - Misyul, S V
AU - Krylova, Svetlana N
AU - Oreshonkov, Aleksandr S.
AU - Ivanenko, A. A.
AU - Zykova, V. A.
AU - Ivanov, Y N
AU - Sukhovsky, A A
AU - Voronov, V. N.
AU - Safonov, I N
AU - Vtyurin, Alexander N.
PY - 2016
DA - 2016/09/12
PB - Royal Society of Chemistry (RSC)
SP - 8472-8486
IS - 43
VL - 18
SN - 1466-8033
ER -
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@article{2016_Krylov,
author = {A. A. Krylov and Maxim S. Molokeev and S V Misyul and Svetlana N Krylova and Aleksandr S. Oreshonkov and A. A. Ivanenko and V. A. Zykova and Y N Ivanov and A A Sukhovsky and V. N. Voronov and I N Safonov and Alexander N. Vtyurin},
title = {Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal},
journal = {CrystEngComm},
year = {2016},
volume = {18},
publisher = {Royal Society of Chemistry (RSC)},
month = {sep},
url = {https://xlink.rsc.org/?DOI=C6CE01144F},
number = {43},
pages = {8472--8486},
doi = {10.1039/c6ce01144f}
}
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Krylov, A. A., et al. “Crystal structure and phase transitions of a layered perovskite-like CsScF4crystal.” CrystEngComm, vol. 18, no. 43, Sep. 2016, pp. 8472-8486. https://xlink.rsc.org/?DOI=C6CE01144F.