Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties
Chang Sik Lim
1
,
Aleksandr Aleksandrovsky
2, 3
,
Maxim S. Molokeev
4, 5
,
Aleksandr S. Oreshonkov
6, 7
,
Denis A Ikonnikov
7
,
V. V. Atuchin
8, 9, 10, 11
2
4
6
Тип публикации: Journal Article
Дата публикации: 2016-08-31
scimago Q2
wos Q1
БС1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
27711792
Inorganic Chemistry
Краткое описание
Triple molybdate NaCaLa(1-x-y)(MoO4)3:xEr3+,yYb3+ (x = y = 0, x = 0.05 and y = 0.45, x = 0.1 and y = 0.2, x = 0.2 and y = 0) phosphors were successfully synthesized for the first time by the microwave sol-gel method. Well-crystallized particles formed after heat treatment at 900 °C for 16 h showed a fine and homogeneous morphology with particle sizes of 2-3 μm. The structures were refined by the Rietveld method in the space group I41/a. The optical properties were examined comparatively using photoluminescence emission and Raman spectroscopy. Under excitation at 980 nm, the NaCaLa0.7(MoO4)3:0.1Er3+,0.2Yb3+ and NaCaLa0.5(MoO4)3:0.05Er3+,0.45Yb3+ particles exhibited a strong 525 nm emission band, a weaker 550 nm emission band in the green region, and three weak 655 nm, 490 nm and 410 nm emission bands in the red, blue and violet regions. The pump power dependence and Commission Internationale de L'Eclairage chromaticity of the upconversion emission intensity were evaluated in detail.
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Lim C. S. et al. Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties // Dalton Transactions. 2016. Vol. 45. No. 39. pp. 15541-15551.
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Lim C. S., Aleksandrovsky A., Molokeev M. S., Oreshonkov A. S., Ikonnikov D. A., Atuchin V. V. Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties // Dalton Transactions. 2016. Vol. 45. No. 39. pp. 15541-15551.
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TY - JOUR
DO - 10.1039/c6dt02378a
UR - https://xlink.rsc.org/?DOI=C6DT02378A
TI - Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties
T2 - Dalton Transactions
AU - Lim, Chang Sik
AU - Aleksandrovsky, Aleksandr
AU - Molokeev, Maxim S.
AU - Oreshonkov, Aleksandr S.
AU - Ikonnikov, Denis A
AU - Atuchin, V. V.
PY - 2016
DA - 2016/08/31
PB - Royal Society of Chemistry (RSC)
SP - 15541-15551
IS - 39
VL - 45
PMID - 27711792
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2016_Lim,
author = {Chang Sik Lim and Aleksandr Aleksandrovsky and Maxim S. Molokeev and Aleksandr S. Oreshonkov and Denis A Ikonnikov and V. V. Atuchin},
title = {Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties},
journal = {Dalton Transactions},
year = {2016},
volume = {45},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=C6DT02378A},
number = {39},
pages = {15541--15551},
doi = {10.1039/c6dt02378a}
}
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MLA
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Lim, Chang Sik, et al. “Triple molybdate scheelite-type upconversion phosphor NaCaLa(MoO4)3:Er3+/Yb3+: structural and spectroscopic properties.” Dalton Transactions, vol. 45, no. 39, Aug. 2016, pp. 15541-15551. https://xlink.rsc.org/?DOI=C6DT02378A.