Dalton Transactions

, volume 46 , issue 5 , pages 1606-1617

Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution

D. Mikhailova ^{1, 2, 3}

N N Kuratieva ⁴

Y. Utsumi ³

A. A. Tsirlin ^{5, 6}

Artem M. Abakumov ^{7, 8, 9}

Michael Schmidt ³

S. Oswald ²

H. Fuess ¹⁰

H. Ehrenberg ¹

Hide authors affiliations Show authors affiliations: 10 affiliations

Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany |

Institute for Complex Materials, IFW Dresden, Helmholtzstr. 20, D-01069 Dresden, Germany |

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, D-01187 Dresden, Germany |

⁴

Institute of Inorganic Chemistry SB Russian Academy of Science, Acad. Lavrentiev Avenue 3, Novosibirsk, Russia |

⁵

National Institute of Chemical Physics and Biophysics, Akadeemia Tee 23, 12618 Tallinn, Estonia |

⁶

Experimental Physics VI, Center for Electronic Correlations and Magnetism, University of Augsburg, D-86159 Augsburg, Germany |

⁷

Skoltech Center for Electrochemical Energy Storage, Skolkovo Institute of Science and Technology, 143026 Moscow, Russia |

⁸

Chemistry department, Moscow State University, Moscow, Russia |

⁹

EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium |

¹⁰

Institute for Materials Science, Darmstadt University for Technology, Alarich Weiss-Straße 2, Darmstadt, Germany |

Publication type: Journal Article

Publication date: 2017-01-01

Royal Society of Chemistry (RSC)

Dalton Transactions

scimago Q2

wos Q1

SJR: 0.653

CiteScore: 6.0

Impact factor: 3.3

ISSN: 14779226, 14779234

DOI: 10.1039/c6dt04389e

Copy DOI

PubMed ID: 28091651

Inorganic Chemistry

Abstract

The V_1−xRe_xO₂ solid solution with 0.03 < x ≤ 0.15 undergoes below 1000 K a phase separation to two isostructural phases with mixed-valence states Re⁴⁺/Re⁶⁺, while only a single phase exists for x ≤ 0.03 and x ≥ 0.30 with Re⁶⁺ and Re⁴⁺, respectively.

Found

1 citation

Gerasimov Evgeny

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PhD in Physics and Mathematics

390 publications, 5 276 citations, 29 reviews

h-index: 36

Boreskov Institute of Catalysis of the Siberian Branch of the Russian Academy of Sciences

Novosibirsk State University

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Mikhailova D. et al. Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution // Dalton Transactions. 2017. Vol. 46. No. 5. pp. 1606-1617.

GOST all authors (up to 50) Copy

Mikhailova D., Kuratieva N. N., Utsumi Y., Tsirlin A. A., Abakumov A. M., Schmidt M., Oswald S., Fuess H., Ehrenberg H. Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution // Dalton Transactions. 2017. Vol. 46. No. 5. pp. 1606-1617.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/c6dt04389e

UR - https://doi.org/10.1039/c6dt04389e

TI - Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution

T2 - Dalton Transactions

AU - Mikhailova, D.

AU - Kuratieva, N N

AU - Utsumi, Y.

AU - Tsirlin, A. A.

AU - Abakumov, Artem M.

AU - Schmidt, Michael

AU - Oswald, S.

AU - Fuess, H.

AU - Ehrenberg, H.

PY - 2017

DA - 2017/01/01

PB - Royal Society of Chemistry (RSC)

SP - 1606-1617

IS - 5

VL - 46

PMID - 28091651

SN - 1477-9226

SN - 1477-9234

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2017_Mikhailova,

author = {D. Mikhailova and N N Kuratieva and Y. Utsumi and A. A. Tsirlin and Artem M. Abakumov and Michael Schmidt and S. Oswald and H. Fuess and H. Ehrenberg},

title = {Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution},

journal = {Dalton Transactions},

year = {2017},

volume = {46},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://doi.org/10.1039/c6dt04389e},

number = {5},

pages = {1606--1617},

doi = {10.1039/c6dt04389e}

}

MLA

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MLA Copy

Mikhailova, D., et al. “Composition-dependent charge transfer and phase separation in the V1−xRexO2 solid solution.” Dalton Transactions, vol. 46, no. 5, Jan. 2017, pp. 1606-1617. https://doi.org/10.1039/c6dt04389e.

Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q2

wos Q1

SJR

0.653

CiteScore

6.0

Impact factor

3.3

ISSN

14779226 (Print)

14779234 (Electronic)

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