A first phosphine oxide-based extractant with high Am/Cm selectivity
Petr I Matveev
1, 2, 3, 4
,
Nataliya E. Borisova
1, 2, 3, 4
,
Nikolai Andreadi
1, 2, 3, 4
,
Gladis G Zakirova
1
,
G G Zakirova
2, 3, 4
,
Vladimir G Petrov
1, 2, 3, 4
,
Elena V Belova
5
,
E. V. Belova
4, 6, 7, 8
,
Stepan N. Kalmykov
1, 5
,
S N Kalmykov
2, 3, 4, 6, 7
,
B. F. Myasoedov
4, 5, 6, 7, 8
3
119991 Moscow
4
Russia
|
7
RAS
8
119071 Moscow
Publication type: Journal Article
Publication date: 2019-01-23
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
30693916
Inorganic Chemistry
Abstract
A new phosphine oxide ligand demonstrates high selectivity for the Am–Cm pair with SF = 2.9–3.5 and the Am–Eu pair with SF = 7.3–8.5 in a range of 0.1–3 M nitric acid. Thermodynamic measurements show that the entropy factor is responsible for selectivity observed in the extraction experiment. The most prevalent complexes of all three metal ions were (Ph2PyPO)2M(NO3)3. According to their DFT modelling, the M–N distances for the Cm ion were larger than those for Am, so the last ion enters deeper into the pseudo-cavity of the ligand, which causes the observed selectivity.
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Total citations:
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Citations from 2024:
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(21.82%)
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Matveev P. I. et al. A first phosphine oxide-based extractant with high Am/Cm selectivity // Dalton Transactions. 2019. Vol. 48. No. 8. pp. 2554-2559.
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Matveev P. I., Borisova N. E., Andreadi N., Zakirova G. G., Zakirova G. G., Petrov V. G., Belova E. V., Belova E. V., Kalmykov S. N., Kalmykov S. N., Myasoedov B. F. A first phosphine oxide-based extractant with high Am/Cm selectivity // Dalton Transactions. 2019. Vol. 48. No. 8. pp. 2554-2559.
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TY - JOUR
DO - 10.1039/c8dt04729d
UR - https://xlink.rsc.org/?DOI=C8DT04729D
TI - A first phosphine oxide-based extractant with high Am/Cm selectivity
T2 - Dalton Transactions
AU - Matveev, Petr I
AU - Borisova, Nataliya E.
AU - Andreadi, Nikolai
AU - Zakirova, Gladis G
AU - Zakirova, G G
AU - Petrov, Vladimir G
AU - Belova, Elena V
AU - Belova, E. V.
AU - Kalmykov, Stepan N.
AU - Kalmykov, S N
AU - Myasoedov, B. F.
PY - 2019
DA - 2019/01/23
PB - Royal Society of Chemistry (RSC)
SP - 2554-2559
IS - 8
VL - 48
PMID - 30693916
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2019_Matveev,
author = {Petr I Matveev and Nataliya E. Borisova and Nikolai Andreadi and Gladis G Zakirova and G G Zakirova and Vladimir G Petrov and Elena V Belova and E. V. Belova and Stepan N. Kalmykov and S N Kalmykov and B. F. Myasoedov},
title = {A first phosphine oxide-based extractant with high Am/Cm selectivity},
journal = {Dalton Transactions},
year = {2019},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C8DT04729D},
number = {8},
pages = {2554--2559},
doi = {10.1039/c8dt04729d}
}
Cite this
MLA
Copy
Matveev, Petr I., et al. “A first phosphine oxide-based extractant with high Am/Cm selectivity.” Dalton Transactions, vol. 48, no. 8, Jan. 2019, pp. 2554-2559. https://xlink.rsc.org/?DOI=C8DT04729D.