Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes
Dominique Leckie
1, 2, 3, 4, 5
,
Nadia T Stephaniuk
1, 2, 3, 4, 5
,
A. Arauzo
6, 7, 8, 9, 10, 11
,
Javier Campo
6, 7, 8, 9, 10, 11
,
Jeremy M. Rawson
1, 2, 3, 4, 5
1
2
Dept of Chemistry & Biochemistry
4
Windsor
5
CANADA
|
6
7
Departamento de Física de la Materia Condensada
10
E-50009 Zaragoza
|
11
SPAIN
|
Тип публикации: Journal Article
Дата публикации: 2019-07-23
scimago Q1
wos Q2
БС1
SJR: 1.037
CiteScore: 7.4
Impact factor: 4.2
ISSN: 13597345, 1364548X
PubMed ID:
31364671
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Краткое описание
Reaction of the methyl-benzodithiazolyl radical (MBDTA) with M(hfac)2 complexes (M = Mn, Co, Zn) affords the complexes M(hfac)2(MBDTA)2. Strong antiferromagnetic exchange interactions are observed between M(II) ions and the two S = 1/2 radicals (M = Mn, Co), whereas weak antiferromagnetic interactions are observed between radicals when using the diamagnetic Zn(II) ion. Strong intermolecular exchange coupling is also evident in Mn(hfac)2(MBDTA)2 and attributed to π*–π* contacts between MBDTA radicals which are absent for the Co and Zn derivatives.
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Leckie D. et al. Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes // Chemical Communications. 2019. Vol. 55. No. 66. pp. 9849-9852.
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Leckie D., Stephaniuk N. T., Arauzo A., Campo J., Rawson J. M. Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes // Chemical Communications. 2019. Vol. 55. No. 66. pp. 9849-9852.
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TY - JOUR
DO - 10.1039/c9cc04271g
UR - https://xlink.rsc.org/?DOI=C9CC04271G
TI - Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes
T2 - Chemical Communications
AU - Leckie, Dominique
AU - Stephaniuk, Nadia T
AU - Arauzo, A.
AU - Campo, Javier
AU - Rawson, Jeremy M.
PY - 2019
DA - 2019/07/23
PB - Royal Society of Chemistry (RSC)
SP - 9849-9852
IS - 66
VL - 55
PMID - 31364671
SN - 1359-7345
SN - 1364-548X
ER -
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@article{2019_Leckie,
author = {Dominique Leckie and Nadia T Stephaniuk and A. Arauzo and Javier Campo and Jeremy M. Rawson},
title = {Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes},
journal = {Chemical Communications},
year = {2019},
volume = {55},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=C9CC04271G},
number = {66},
pages = {9849--9852},
doi = {10.1039/c9cc04271g}
}
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Leckie, Dominique, et al. “Exploring through-bond and through-space magnetic communication in 1,3,2-dithiazolyl radical complexes.” Chemical Communications, vol. 55, no. 66, Jul. 2019, pp. 9849-9852. https://xlink.rsc.org/?DOI=C9CC04271G.
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