Royal Society of Chemistry (RSC)
CrystEngComm
,  volume 21 ,  issue 38 ,  pages 5693-5698

Unusual isomorphism in crystals of organic solvates with hydrazine and water

Publication type: Journal Article
Publication date: 2019-08-28
Royal Society of Chemistry (RSC)
scimago Q2
wos Q2
SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
An unusual isomorphism of 18-crown-6 hydrazine disolvate C12H24O6·2N2H4 (1) and 18-crown-6 tetrahydrate (2) is observed. The isomorphous substitution of hydrazine by water molecules is found for the first time in the structures of tetrabutylammonium acetate hydrazine solvates hydrous Bu4N+AcO−·0.9(N2H4)·0.1(H2O) (3) and anhydrous Bu4N+AcO−·N2H4 (4). Surprisingly, the nature of these isomorphous relationships is completely different from the well-known isostructurality of organic hydrogen peroxide/water solvates.
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Navasardyan M. A. et al. Unusual isomorphism in crystals of organic solvates with hydrazine and water // CrystEngComm. 2019. Vol. 21. No. 38. pp. 5693-5698.
GOST all authors (up to 50) Copy
Navasardyan M. A., Kuz'mina L. G., Churakov A. V. Unusual isomorphism in crystals of organic solvates with hydrazine and water // CrystEngComm. 2019. Vol. 21. No. 38. pp. 5693-5698.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/c9ce00978g
UR - https://xlink.rsc.org/?DOI=C9CE00978G
TI - Unusual isomorphism in crystals of organic solvates with hydrazine and water
T2 - CrystEngComm
AU - Navasardyan, Mger A.
AU - Kuz'mina, Lyudmila G.
AU - Churakov, Andrei V.
PY - 2019
DA - 2019/08/28
PB - Royal Society of Chemistry (RSC)
SP - 5693-5698
IS - 38
VL - 21
SN - 1466-8033
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2019_Navasardyan,
author = {Mger A. Navasardyan and Lyudmila G. Kuz'mina and Andrei V. Churakov},
title = {Unusual isomorphism in crystals of organic solvates with hydrazine and water},
journal = {CrystEngComm},
year = {2019},
volume = {21},
publisher = {Royal Society of Chemistry (RSC)},
month = {aug},
url = {https://xlink.rsc.org/?DOI=C9CE00978G},
number = {38},
pages = {5693--5698},
doi = {10.1039/c9ce00978g}
}
MLA
Cite this
MLA Copy
Navasardyan, Mger A., et al. “Unusual isomorphism in crystals of organic solvates with hydrazine and water.” CrystEngComm, vol. 21, no. 38, Aug. 2019, pp. 5693-5698. https://xlink.rsc.org/?DOI=C9CE00978G.