CrystEngComm

, том 21 , издание 38 , страницы 5693-5698

Unusual isomorphism in crystals of organic solvates with hydrazine and water

Тип публикации: Journal Article

Дата публикации: 2019-08-28

Royal Society of Chemistry (RSC)

CrystEngComm

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SJR: 0.52

CiteScore: 5.2

Impact factor: 2.6

ISSN: 14668033

DOI: 10.1039/c9ce00978g

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General Chemistry

Condensed Matter Physics

General Materials Science

Краткое описание

An unusual isomorphism of 18-crown-6 hydrazine disolvate C12H24O6·2N2H4 (1) and 18-crown-6 tetrahydrate (2) is observed. The isomorphous substitution of hydrazine by water molecules is found for the first time in the structures of tetrabutylammonium acetate hydrazine solvates hydrous Bu4N+AcO−·0.9(N2H4)·0.1(H2O) (3) and anhydrous Bu4N+AcO−·N2H4 (4). Surprisingly, the nature of these isomorphous relationships is completely different from the well-known isostructurality of organic hydrogen peroxide/water solvates.

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Журналы

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Crystal Growth and Design	Crystal Growth and Design, 1, 33.33% Crystal Growth and Design 1 публикация, 33.33%
Molecules	Molecules, 1, 33.33% Molecules 1 публикация, 33.33%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 1, 33.33% Journal of Materials Chemistry A 1 публикация, 33.33%
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American Chemical Society (ACS)	American Chemical Society (ACS), 1, 33.33% American Chemical Society (ACS) 1 публикация, 33.33%
MDPI	MDPI, 1, 33.33% MDPI 1 публикация, 33.33%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 33.33% Royal Society of Chemistry (RSC) 1 публикация, 33.33%
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Navasardyan M. A. et al. Unusual isomorphism in crystals of organic solvates with hydrazine and water // CrystEngComm. 2019. Vol. 21. No. 38. pp. 5693-5698.

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Navasardyan M. A., Kuz'mina L. G., Churakov A. V. Unusual isomorphism in crystals of organic solvates with hydrazine and water // CrystEngComm. 2019. Vol. 21. No. 38. pp. 5693-5698.

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TY - JOUR

DO - 10.1039/c9ce00978g

UR - https://xlink.rsc.org/?DOI=C9CE00978G

TI - Unusual isomorphism in crystals of organic solvates with hydrazine and water

T2 - CrystEngComm

AU - Navasardyan, Mger A.

AU - Kuz'mina, Lyudmila G.

AU - Churakov, Andrei V.

PY - 2019

DA - 2019/08/28

PB - Royal Society of Chemistry (RSC)

SP - 5693-5698

IS - 38

VL - 21

SN - 1466-8033

ER -

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@article{2019_Navasardyan,

author = {Mger A. Navasardyan and Lyudmila G. Kuz'mina and Andrei V. Churakov},

title = {Unusual isomorphism in crystals of organic solvates with hydrazine and water},

journal = {CrystEngComm},

year = {2019},

volume = {21},

publisher = {Royal Society of Chemistry (RSC)},

month = {aug},

url = {https://xlink.rsc.org/?DOI=C9CE00978G},

number = {38},

pages = {5693--5698},

doi = {10.1039/c9ce00978g}

}

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Navasardyan, Mger A., et al. “Unusual isomorphism in crystals of organic solvates with hydrazine and water.” CrystEngComm, vol. 21, no. 38, Aug. 2019, pp. 5693-5698. https://xlink.rsc.org/?DOI=C9CE00978G.