Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes
Svetlana P. Petrosyants
1, 2, 3, 4, 5
,
Konstantin A Babeshkin
1, 2, 3, 4, 5
,
Andrey V Gavrikov
1, 2, 3, 4, 5
,
Andrey B. Ilyukhin
1, 2, 3, 4, 5
,
Ekaterina Belova
1, 2, 3, 4, 5, 6, 7
,
Nikolay N. Efimov
1, 2, 3, 4, 5
3
RUSSIAN ACADEMY OF SCIENCES
4
119991 Moscow
5
RUSSIAN FEDERATION
|
Publication type: Journal Article
Publication date: 2019-07-23
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
31384881
Inorganic Chemistry
Abstract
We prepared and studied two similar series of Er and Yb thiocyanates, involving [Ln(H2O)5(NCS)3]·H2O (1Er, 1Yb) as well as the molecular and ionic complexes with 2,2′-bipyridine (bpy) and 1,10-phenantroline (phen), [Ln(H2O)(bpy)2(NCS)3]·0.5(bpy)·H2O (2Er, 2Yb), [Ln(H2O)(phen)2(NCS)3]·phen·0.5H2O (3Er, 3Yb), [Hbpy][Ln(bpy)2(NCS)4]·H2O (4Er, 4Yb) and [Hphen][Ln(phen)2(NCS)4] (5Er, 5Yb). All the complexes were found to exhibit the properties of field-induced single-molecule magnets. For 1Yb, the effective value of the energy barrier for magnetization reversal, Δeff/kB, equals to 50 K, which is among the highest ones currently known for molecular SMMs based on Yb3+. The obtained data are discussed involving essential structural features of the complexes, namely the configuration of the Ln environment, i.e. its composition and geometry as well as mutual distribution of different donating centers. To the best of our knowledge, this work also involves experimental investigation of the largest and thus sufficiently representative series of similar mononuclear SMMs based on Er and Yb within one study.
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Petrosyants S. P. et al. Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes // Dalton Transactions. 2019. Vol. 48. No. 33. pp. 12644-12655.
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Petrosyants S. P., Babeshkin K. A., Gavrikov A. V., Ilyukhin A. B., Belova E., Efimov N. N. Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes // Dalton Transactions. 2019. Vol. 48. No. 33. pp. 12644-12655.
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TY - JOUR
DO - 10.1039/c9dt02260k
UR - https://xlink.rsc.org/?DOI=C9DT02260K
TI - Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes
T2 - Dalton Transactions
AU - Petrosyants, Svetlana P.
AU - Babeshkin, Konstantin A
AU - Gavrikov, Andrey V
AU - Ilyukhin, Andrey B.
AU - Belova, Ekaterina
AU - Efimov, Nikolay N.
PY - 2019
DA - 2019/07/23
PB - Royal Society of Chemistry (RSC)
SP - 12644-12655
IS - 33
VL - 48
PMID - 31384881
SN - 1477-9226
SN - 1477-9234
ER -
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@article{2019_Petrosyants,
author = {Svetlana P. Petrosyants and Konstantin A Babeshkin and Andrey V Gavrikov and Andrey B. Ilyukhin and Ekaterina Belova and Nikolay N. Efimov},
title = {Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes},
journal = {Dalton Transactions},
year = {2019},
volume = {48},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=C9DT02260K},
number = {33},
pages = {12644--12655},
doi = {10.1039/c9dt02260k}
}
Cite this
MLA
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Petrosyants, Svetlana P., et al. “Towards comparative investigation of Er- and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of heteroleptic thiocyanate complexes.” Dalton Transactions, vol. 48, no. 33, Jul. 2019, pp. 12644-12655. https://xlink.rsc.org/?DOI=C9DT02260K.