Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor
Yanding Li
1, 2, 3, 4, 5, 6, 7
,
Benginur Demir
2, 4, 5, 6, 7, 8, 9
,
Leida M Vázquez Ramos
2, 4, 5, 6, 7, 8, 9
,
Mingjie Chen
2, 4, 5, 6, 7
,
James Dumesic
2, 4, 5, 6, 7, 8, 9
,
John Ralph
1, 2, 3, 4, 5, 6, 7, 10
2
3
Department of Biological Systems Engineering
5
Madison
|
6
Usa
|
7
DOE Great Lakes Bioenergy Research Center
9
Department of Chemical and Biological Engineering
Publication type: Journal Article
Publication date: 2019-04-25
scimago Q1
wos Q1
SJR: 1.928
CiteScore: 16.1
Impact factor: 9.2
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
Industrial biorefineries remain limited due to inefficient valorization of their lignin streams. Rarely can a lignin depolymerization method be combined with a current polysaccharide-centric biorefinery process. Hydrogenolysis is among the more promising methods for depolymerizing lignin on an industrial scale. We performed reaction kinetics and mechanistic studies on lignin model compounds to understand lignin hydrogenolysis pathways, demonstrating that lignin end-units and internal units react significantly differently. Understanding the reaction mechanism and its sensitivity to variables helped us establish a continuous lignin upgrading process from various fractionated lignins. Near-theoretical yields of lignin platform monomers with >80% overall product selectivity were obtained in a continuous hydrogenolysis process using a Pd/C catalyst.
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85
Total citations:
85
Citations from 2024:
29
(34.12%)
Cite this
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MLA
Cite this
GOST
Copy
Li Y. et al. Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor // Green Chemistry. 2019. Vol. 21. No. 13. pp. 3561-3572.
GOST all authors (up to 50)
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Li Y., Demir B., Vázquez Ramos L. M., Chen M., Dumesic J., Ralph J. Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor // Green Chemistry. 2019. Vol. 21. No. 13. pp. 3561-3572.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/c9gc00986h
UR - https://xlink.rsc.org/?DOI=C9GC00986H
TI - Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor
T2 - Green Chemistry
AU - Li, Yanding
AU - Demir, Benginur
AU - Vázquez Ramos, Leida M
AU - Chen, Mingjie
AU - Dumesic, James
AU - Ralph, John
PY - 2019
DA - 2019/04/25
PB - Royal Society of Chemistry (RSC)
SP - 3561-3572
IS - 13
VL - 21
SN - 1463-9262
SN - 1463-9270
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Li,
author = {Yanding Li and Benginur Demir and Leida M Vázquez Ramos and Mingjie Chen and James Dumesic and John Ralph},
title = {Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor},
journal = {Green Chemistry},
year = {2019},
volume = {21},
publisher = {Royal Society of Chemistry (RSC)},
month = {apr},
url = {https://xlink.rsc.org/?DOI=C9GC00986H},
number = {13},
pages = {3561--3572},
doi = {10.1039/c9gc00986h}
}
Cite this
MLA
Copy
Li, Yanding, et al. “Kinetic and mechanistic insights into hydrogenolysis of lignin to monomers in a continuous flow reactor.” Green Chemistry, vol. 21, no. 13, Apr. 2019, pp. 3561-3572. https://xlink.rsc.org/?DOI=C9GC00986H.