Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2 Te]+I- (R = Ph, Fc)
Yu. V. Torubaev
1, 2, 3, 4
,
Fedor Dolgushin
5
,
Fedor M. Dolgushin
3, 4, 6
,
I. V. Skabitsky
1
,
Ivan V Skabitsky
2, 3, 4
,
Alexandra E Popova
1, 2, 3, 4
3
Moscow
4
Russia
|
5
Publication type: Journal Article
Publication date: 2019-07-02
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
The crystal structures of PhMeTeI2 (1), FcMeTeI2 (2) and [FcMe2Te]+I− (3), which are the products of iodomethylation of R2Te2 (R = Ph, ferrocenyl (Fc)) by MeI, are reported. Analysis of secondary interactions and packing patterns in 1–3 revealed Te⋯πPh chalcogen bonding in 1, unusual structural parallels between 2 and 3, and unprecedented isomorphic substitution in the crystals of 3 with an admixture of Te–I ionized molecules 2 [FcMeTeI+]I−. In summary, we are discussing the 3c-4e bonding model as a general, seamless scheme for the geometry and electronic structure of hypervalent tellurium atom coordination in both the isolated molecules and crystals, which overcomes the confusing division between the molecular and supramolecular geometry.
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Total citations:
9
Citations from 2024:
1
(11.11%)
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Torubaev Y. V. et al. Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2Te]+I- (R = Ph, Fc) // New Journal of Chemistry. 2019. Vol. 43. No. 31. pp. 12225-12232.
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Torubaev Y. V., Dolgushin F., Dolgushin F. M., Skabitsky I. V., Skabitsky I. V., Popova A. E. Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2Te]+I- (R = Ph, Fc) // New Journal of Chemistry. 2019. Vol. 43. No. 31. pp. 12225-12232.
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TY - JOUR
DO - 10.1039/c9nj02318f
UR - https://xlink.rsc.org/?DOI=C9NJ02318F
TI - Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2Te]+I- (R = Ph, Fc)
T2 - New Journal of Chemistry
AU - Torubaev, Yu. V.
AU - Dolgushin, Fedor
AU - Dolgushin, Fedor M.
AU - Skabitsky, I. V.
AU - Skabitsky, Ivan V
AU - Popova, Alexandra E
PY - 2019
DA - 2019/07/02
PB - Royal Society of Chemistry (RSC)
SP - 12225-12232
IS - 31
VL - 43
SN - 1144-0546
SN - 1369-9261
ER -
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BibTex (up to 50 authors)
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@article{2019_Torubaev,
author = {Yu. V. Torubaev and Fedor Dolgushin and Fedor M. Dolgushin and I. V. Skabitsky and Ivan V Skabitsky and Alexandra E Popova},
title = {Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2Te]+I- (R = Ph, Fc)},
journal = {New Journal of Chemistry},
year = {2019},
volume = {43},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=C9NJ02318F},
number = {31},
pages = {12225--12232},
doi = {10.1039/c9nj02318f}
}
Cite this
MLA
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Torubaev, Yu. V., et al. “Isomorphic substitution in molecular crystals and geometry of hypervalent tellurium: Comments inspired by a case study of RMeTeI2 and [RMe2Te]+I- (R = Ph, Fc).” New Journal of Chemistry, vol. 43, no. 31, Jul. 2019, pp. 12225-12232. https://xlink.rsc.org/?DOI=C9NJ02318F.