Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage.
Тип публикации: Journal Article
Дата публикации: 2019-05-17
scimago Q2
wos Q2
БС1
SJR: 0.600
CiteScore: 5.2
Impact factor: 2.7
ISSN: 14770520, 14770539
PubMed ID:
31169856
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
We report an "inversed" Arbuzov reaction of the fullerene derivatives C60Ar5Cl with trialkyl phosphites P(OR)3 producing alkylated fullerene derivatives C60Ar5R (R = Me, Et, iPr, nBu) with almost quantitative yields. This reaction provides a convenient synthetic route for the preparation of a large variety of functionalized fullerene derivatives with tailored properties, e.g. water-soluble compounds demonstrating promising antiviral activities against HCMV, HSV1, HIV and several influenza virus strains.
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Kraevaya O. A. et al. Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage. // Organic and Biomolecular Chemistry. 2019. Vol. 17. No. 30. pp. 7155-7160.
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Kraevaya O. A. et al. Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage. // Organic and Biomolecular Chemistry. 2019. Vol. 17. No. 30. pp. 7155-7160.
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TY - JOUR
DO - 10.1039/c9ob00593e
UR - https://xlink.rsc.org/?DOI=C9OB00593E
TI - Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage.
T2 - Organic and Biomolecular Chemistry
AU - Kraevaya, Olga A
AU - Peregudov, A. S.
AU - Peregudov, Alexander S.
AU - Troyanov, Sergey
AU - Godovikov, Ivan A
AU - Godovikov, Ivan
AU - Fedorova, N. E.
AU - Климова, Р. Р.
AU - Sergeeva, Vasilina
AU - Sergeeva, Vasilina A
AU - Kameneva, Larisa V.
AU - Ershova, Elizaveta
AU - Ershova, Elizaveta S.
AU - Martynenko, V.M
AU - Martynenko, Vyacheslav M
AU - Claes, Sandra
AU - Kushch, A. A.
AU - Kostyuk, Svetlana
AU - Kostyuk, Svetlana V.
AU - Schols, Dominique
AU - Shestakov, Alexander F.
AU - Troshin, Pavel A.
PY - 2019
DA - 2019/05/17
PB - Royal Society of Chemistry (RSC)
SP - 7155-7160
IS - 30
VL - 17
PMID - 31169856
SN - 1477-0520
SN - 1477-0539
ER -
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@article{2019_Kraevaya,
author = {Olga A Kraevaya and A. S. Peregudov and Alexander S. Peregudov and Sergey Troyanov and Ivan A Godovikov and Ivan Godovikov and N. E. Fedorova and Р. Р. Климова and Vasilina Sergeeva and Vasilina A Sergeeva and Larisa V. Kameneva and Elizaveta Ershova and Elizaveta S. Ershova and V.M Martynenko and Vyacheslav M Martynenko and Sandra Claes and A. A. Kushch and Svetlana Kostyuk and Svetlana V. Kostyuk and Dominique Schols and Alexander F. Shestakov and Pavel A. Troshin and others},
title = {Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage.},
journal = {Organic and Biomolecular Chemistry},
year = {2019},
volume = {17},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=C9OB00593E},
number = {30},
pages = {7155--7160},
doi = {10.1039/c9ob00593e}
}
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Kraevaya, Olga A., et al. “Diversion of the Arbuzov reaction: alkylation of C-Cl instead of phosphonic ester formation on the fullerene cage..” Organic and Biomolecular Chemistry, vol. 17, no. 30, May. 2019, pp. 7155-7160. https://xlink.rsc.org/?DOI=C9OB00593E.
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