Organic and Biomolecular Chemistry

, том 18 , издание 1 , страницы 81-85

Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization

Тип публикации: Journal Article

Дата публикации: 2020-01-01

Royal Society of Chemistry (RSC)

Organic and Biomolecular Chemistry

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SJR: 0.6

CiteScore: 5.2

Impact factor: 2.7

ISSN: 14770520, 14770539

DOI: 10.1039/c9ob02363a

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PubMed ID: 31782470

Organic Chemistry

Biochemistry

Physical and Theoretical Chemistry

Краткое описание

A ruthenium-catalyzed cycloisomerization of 3-amino-4-alkynyl-2H-chromen-2-ones via 1,2-carbon migration was developed. Various 1-arylchromeno[3,4-b]pyrrol-4(3H)-ones were synthesized in good to excellent yields. The reaction was applied to the formal total synthesis of marine natural products Ningalin B and Lamellarin H. The efficient synthesis of γ-butyrolactone-fused pyrrole derivatives was also achieved.

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Watanabe T. et al. Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization // Organic and Biomolecular Chemistry. 2020. Vol. 18. No. 1. pp. 81-85.

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Watanabe T., Mutoh Y., SAITO S. Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization // Organic and Biomolecular Chemistry. 2020. Vol. 18. No. 1. pp. 81-85.

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TY - JOUR

DO - 10.1039/c9ob02363a

UR - https://xlink.rsc.org/?DOI=C9OB02363A

TI - Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization

T2 - Organic and Biomolecular Chemistry

AU - Watanabe, Takuma

AU - Mutoh, Yuichiro

AU - SAITO, Shinichi

PY - 2020

DA - 2020/01/01

PB - Royal Society of Chemistry (RSC)

SP - 81-85

IS - 1

VL - 18

PMID - 31782470

SN - 1477-0520

SN - 1477-0539

ER -

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@article{2020_Watanabe,

author = {Takuma Watanabe and Yuichiro Mutoh and Shinichi SAITO},

title = {Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization},

journal = {Organic and Biomolecular Chemistry},

year = {2020},

volume = {18},

publisher = {Royal Society of Chemistry (RSC)},

month = {jan},

url = {https://xlink.rsc.org/?DOI=C9OB02363A},

number = {1},

pages = {81--85},

doi = {10.1039/c9ob02363a}

}

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Watanabe, Takuma, et al. “Synthesis of lactone-fused pyrroles by ruthenium-catalyzed 1,2-carbon migration-cycloisomerization.” Organic and Biomolecular Chemistry, vol. 18, no. 1, Jan. 2020, pp. 81-85. https://xlink.rsc.org/?DOI=C9OB02363A.