Polymer Chemistry

, volume 10 , issue 26 , pages 3604-3609

An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes

Ji Li ¹

Ji Li ^{1, 2, 3, 4, 5}

Jia Shuai Liu ⁶

Jia-Shuai Liu ^{5, 6, 7, 8, 9, 10}

Xiao Yan Wang ^{5, 6, 7, 8, 9, 10}

Jun-Fang Li ^{5, 6, 7, 8, 9, 10}

Zhou Chen ^{5, 6, 7, 8, 9, 10}

Saihu Liao ^{1, 2, 3, 4, 5}

Xiuli Sun ^{5, 6, 7, 8, 9, 10, 11, 12}

Yong Tang ^{5, 6, 7, 8, 9, 10}

Hide authors affiliations Show authors affiliations: 12 affiliations

College of Chemistry, Fuzhou University, 2 Xueyuan Road, Fuzhou, Fujian 350108, China |

College of Chemistry

FuZhou University |

⁴

Fuzhou |

⁵

CHINA |

⁶

State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai, China |

⁷

State Key Laboratory of Organometallic Chemistry

⁸

Shanghai Institute of Organic Chemistry |

⁹

Chinese Academy of sciences

¹⁰

Shanghai |

¹¹

CAS Key Laboratory of Energy Regulation Materials, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China |

¹²

Fujian Institute of Innovation, Chinese Academy of Sciences, China |

Publication type: Journal Article

Publication date: 2019-05-23

Royal Society of Chemistry (RSC)

Polymer Chemistry

scimago Q1

wos Q2

SJR: 0.842

CiteScore: 7.6

Impact factor: 3.9

ISSN: 17599954, 17599962

DOI: 10.1039/c9py00009g

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Organic Chemistry

Biochemistry

Polymers and Plastics

Bioengineering

Abstract

A series of fluorinated polyolefins have been efficiently synthesized via the copolymerization of ethylene with 5-(perfluoro-n-alkyl)norbornenes by employing a class of [ONS] titanium catalysts, which possess an open coordination space environment and exhibit excellent tolerance towards fluorine atoms and excellent catalytic activity (up to 1.60 × 106 g (mol h atm)−1). Fluorinated polyolefins with high fluorine contents (up to 44.0 wt%) and high molecular weights (3.5–15.9 × 104 g mol−1) could be obtained under mild conditions. DSC analysis indicated that incorporation of the fluorinated comonomers into polyethylene significantly influences the crystallinity of the polymers (Tm), while it has little influence on the polymer stability.

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GOST |

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GOST Copy

Li J. et al. An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes // Polymer Chemistry. 2019. Vol. 10. No. 26. pp. 3604-3609.

GOST all authors (up to 50) Copy

Li J., Ji Li, Liu J. S., Liu J., Wang X. Y., Li J., Chen Z., Liao S., Sun X., Tang Y. An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes // Polymer Chemistry. 2019. Vol. 10. No. 26. pp. 3604-3609.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/c9py00009g

UR - https://xlink.rsc.org/?DOI=C9PY00009G

TI - An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes

T2 - Polymer Chemistry

AU - Li, Ji

AU - Ji Li

AU - Liu, Jia Shuai

AU - Liu, Jia-Shuai

AU - Wang, Xiao Yan

AU - Li, Jun-Fang

AU - Chen, Zhou

AU - Liao, Saihu

AU - Sun, Xiuli

AU - Tang, Yong

PY - 2019

DA - 2019/05/23

PB - Royal Society of Chemistry (RSC)

SP - 3604-3609

IS - 26

VL - 10

SN - 1759-9954

SN - 1759-9962

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2019_Li,

author = {Ji Li and Ji Li and Jia Shuai Liu and Jia-Shuai Liu and Xiao Yan Wang and Jun-Fang Li and Zhou Chen and Saihu Liao and Xiuli Sun and Yong Tang},

title = {An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes},

journal = {Polymer Chemistry},

year = {2019},

volume = {10},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=C9PY00009G},

number = {26},

pages = {3604--3609},

doi = {10.1039/c9py00009g}

}

MLA

Cite this

MLA Copy

Li, Ji, et al. “An efficient and mild route to highly fluorinated polyolefins via copolymerization of ethylene and 5-perfluoroalkylnorbornenes.” Polymer Chemistry, vol. 10, no. 26, May. 2019, pp. 3604-3609. https://xlink.rsc.org/?DOI=C9PY00009G.

Publisher

Royal Society of Chemistry (RSC)

Journal

Polymer Chemistry

scimago Q1

wos Q2

SJR

0.842

CiteScore

7.6

Impact factor

3.9

ISSN

17599954 (Print)

17599962 (Electronic)