Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation
Miao-Chang Liu
1, 2, 3, 4, 5
,
Wei Liu
5, 6, 7, 8
,
Hua-Yue Wu
5, 6, 7, 8
,
Yun Bing Zhou
5, 6, 7, 8
,
Yun-Bing Zhou
5, 6, 7, 8
,
Qiuping Ding
1, 2, 3, 4, 5
,
Yi-Yuan Peng
1, 2, 3, 4, 5
,
Yiyuan Peng
1, 2, 3, 4, 5
1
Key Laboratory of Functional Small Organic Molecules
2
Ministry of Education
3
JiangXi Normal University
|
4
Nanchang 330022
|
5
CHINA
|
6
College of Chemistry and Materials Engineering
8
Wenzhou 325035
|
Publication type: Journal Article
Publication date: 2020-01-01
scimago Q1
wos Q1
SJR: 1.068
CiteScore: 8.2
Impact factor: 4.7
ISSN: 20524110, 20524129
Organic Chemistry
Abstract
(NH4)2S2O8-mediated decarboxylative trifluoroalkylation of alkenes with 3,3,3-trifluoro-2,2-dimethylpropanoic acid under metal-free conditions has been described. This approach provides a new pathway to directly synthesize a series of CMe2CF3-containing chroman-4-ones from simple chemical feedstocks. Particularly, the utility of the method was demonstrated by its application in the synthesis of CMe2CF3-derived TRPV1 precursors.
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Total citations:
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Citations from 2025:
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Liu M. et al. Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation // Organic Chemistry Frontiers. 2020. Vol. 7. No. 3. pp. 487-491.
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Liu M., Liu W., Wu H., Zhou Y. B., Zhou Y., Ding Q., Peng Y., Peng Y. Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation // Organic Chemistry Frontiers. 2020. Vol. 7. No. 3. pp. 487-491.
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RIS
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TY - JOUR
DO - 10.1039/c9qo01283d
UR - https://xlink.rsc.org/?DOI=C9QO01283D
TI - Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation
T2 - Organic Chemistry Frontiers
AU - Liu, Miao-Chang
AU - Liu, Wei
AU - Wu, Hua-Yue
AU - Zhou, Yun Bing
AU - Zhou, Yun-Bing
AU - Ding, Qiuping
AU - Peng, Yi-Yuan
AU - Peng, Yiyuan
PY - 2020
DA - 2020/01/01
PB - Royal Society of Chemistry (RSC)
SP - 487-491
IS - 3
VL - 7
SN - 2052-4110
SN - 2052-4129
ER -
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BibTex (up to 50 authors)
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@article{2020_Liu,
author = {Miao-Chang Liu and Wei Liu and Hua-Yue Wu and Yun Bing Zhou and Yun-Bing Zhou and Qiuping Ding and Yi-Yuan Peng and Yiyuan Peng},
title = {Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation},
journal = {Organic Chemistry Frontiers},
year = {2020},
volume = {7},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=C9QO01283D},
number = {3},
pages = {487--491},
doi = {10.1039/c9qo01283d}
}
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Liu, Miao-Chang, et al. “Transition-metal-free synthesis of CMe2CF3-containing chroman-4-ones via decarboxylative trifluoroalkylation.” Organic Chemistry Frontiers, vol. 7, no. 3, Jan. 2020, pp. 487-491. https://xlink.rsc.org/?DOI=C9QO01283D.