Royal Society of Chemistry (RSC)
New Journal of Chemistry
,  volume 44 ,  issue 33 ,  pages 13944-13951

Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates

Victor P Zelenov 1, 2, 3, 4, 5
, 
Evgeny Yu Gorshkov 1, 2, 3, 4, 5
, 
Mikhail V Zavaruev 1, 2, 3, 4, 5, 6, 7
, 
Artem O. Dmitrienko 5, 6, 7, 8, 9, 10
, 
I. A. Troyan 3, 5, 11, 12, 13
, 
Alla Pivkina 3, 5, 13, 14, 15
, 
Dmitry Khakimov 1, 2, 3, 4, 5
, 
A.V. Pavlikov 5, 8, 9, 10, 16, 17
1
 
2
 
3
 
RUSSIAN ACADEMY OF SCIENCES
4
 
119991 Moscow
5
 
RUSSIAN FEDERATION | 
6
 
7
 
DEPARTMENT OF CHEMISTRY
8
 
9
 
Leninskie Gory
10
 
Moscow 119991
11
 
12
 
13
 
Moscow
14
 
15
 
16
 
17
 
Department of Physics
Publication type: Journal Article
Publication date: 2020-07-20
Royal Society of Chemistry (RSC)
scimago Q2
wos Q3
SJR: 0.493
CiteScore: 5.0
Impact factor: 2.5
ISSN: 11440546, 13699261
Materials Chemistry
General Chemistry
Catalysis
Abstract
Nitronium borates of NO2[B(OX)4] type with X = CF3CO and NO2 as ligands were synthesized, and their structures were determined by powder X-ray diffraction. Crystalline NO2[B(ONO2)4] is relatively stable at room temperature and undergoes transformation to B2O3 upon heating. The [B(CF3COO)4]− anion was obtained for the first time and characterized as a structural fragment of a solid compound. The possibility of reversible modification of the complex anion by replacement of the nitrate or trifluoroacetate ligand was demonstrated for the first time by the mutual transformations of NO2[B(ONO2)4] and NO2[B(CF3COO)4].
Found 
Found 

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GOST Copy
Zelenov V. P. et al. Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates // New Journal of Chemistry. 2020. Vol. 44. No. 33. pp. 13944-13951.
GOST all authors (up to 50) Copy
Zelenov V. P., Gorshkov E. Yu., Zavaruev M. V., Dmitrienko A. O., Troyan I. A., Pivkina A., Khakimov D., Pavlikov A. Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates // New Journal of Chemistry. 2020. Vol. 44. No. 33. pp. 13944-13951.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/d0nj02835e
UR - https://xlink.rsc.org/?DOI=D0NJ02835E
TI - Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates
T2 - New Journal of Chemistry
AU - Zelenov, Victor P
AU - Gorshkov, Evgeny Yu
AU - Zavaruev, Mikhail V
AU - Dmitrienko, Artem O.
AU - Troyan, I. A.
AU - Pivkina, Alla
AU - Khakimov, Dmitry
AU - Pavlikov, A.V.
PY - 2020
DA - 2020/07/20
PB - Royal Society of Chemistry (RSC)
SP - 13944-13951
IS - 33
VL - 44
SN - 1144-0546
SN - 1369-9261
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Zelenov,
author = {Victor P Zelenov and Evgeny Yu Gorshkov and Mikhail V Zavaruev and Artem O. Dmitrienko and I. A. Troyan and Alla Pivkina and Dmitry Khakimov and A.V. Pavlikov},
title = {Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates},
journal = {New Journal of Chemistry},
year = {2020},
volume = {44},
publisher = {Royal Society of Chemistry (RSC)},
month = {jul},
url = {https://xlink.rsc.org/?DOI=D0NJ02835E},
number = {33},
pages = {13944--13951},
doi = {10.1039/d0nj02835e}
}
MLA
Cite this
MLA Copy
Zelenov, Victor P., et al. “Synthesis and mutual transformations of nitronium tetrakis(nitrooxy)- and tetrakis(2,2,2-trifluoroacetoxy)borates.” New Journal of Chemistry, vol. 44, no. 33, Jul. 2020, pp. 13944-13951. https://xlink.rsc.org/?DOI=D0NJ02835E.