New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries
Elena Romadina
1, 2, 3, 4, 5, 6, 7
,
Ivan A Volodin
1, 3, 4, 5, 6
,
Keith J Stevenson
1, 3, 4, 5, 6
,
Pavel A. Troshin
2, 6, 7, 8, 9
3
Center for Energy Science and Technology
5
Moscow
6
RUSSIAN FEDERATION
|
8
RUSSIAN ACADEMY OF SCIENCES
9
Moscow region
Publication type: Journal Article
Publication date: 2021-02-18
scimago Q1
wos Q1
SJR: 2.462
CiteScore: 16.7
Impact factor: 9.5
ISSN: 20507488, 20507496, 09599428, 13645501
General Chemistry
General Materials Science
Renewable Energy, Sustainability and the Environment
Abstract
A series of arylamines bearing oligoethylene glycol ether solubilizing moieties were designed and comprehensively evaluated as promising catholyte materials for non-aqueous redox flow batteries (RFBs). The triphenylamine core maintains the chemical stability of the radical cation, the ethylene glycol chains enhance the solubility up to complete miscibility with organic solvents, and the electron-withdrawing bromine substituents increase the redox potential of the compounds up to 0.61 V vs. Ag/AgNO3. The best material showed 99% coulombic efficiency in combination with good stability in over 50 charge–discharge cycles in laboratory RFB cells. The designed triarylamine-based catholyte materials appear promising for the development of next-generation high-voltage and high-capacity RFBs.
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Metrics
22
Total citations:
22
Citations from 2024:
5
(22.73%)
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GOST
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Romadina E. et al. New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries // Journal of Materials Chemistry A. 2021. Vol. 9. No. 13. pp. 8303-8307.
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Romadina E., Volodin I. A., Stevenson K. J., Troshin P. A. New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries // Journal of Materials Chemistry A. 2021. Vol. 9. No. 13. pp. 8303-8307.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1039/d0ta11860e
UR - https://xlink.rsc.org/?DOI=D0TA11860E
TI - New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries
T2 - Journal of Materials Chemistry A
AU - Romadina, Elena
AU - Volodin, Ivan A
AU - Stevenson, Keith J
AU - Troshin, Pavel A.
PY - 2021
DA - 2021/02/18
PB - Royal Society of Chemistry (RSC)
SP - 8303-8307
IS - 13
VL - 9
SN - 2050-7488
SN - 2050-7496
SN - 0959-9428
SN - 1364-5501
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2021_Romadina,
author = {Elena Romadina and Ivan A Volodin and Keith J Stevenson and Pavel A. Troshin},
title = {New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries},
journal = {Journal of Materials Chemistry A},
year = {2021},
volume = {9},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://xlink.rsc.org/?DOI=D0TA11860E},
number = {13},
pages = {8303--8307},
doi = {10.1039/d0ta11860e}
}
Cite this
MLA
Copy
Romadina, Elena, et al. “New highly soluble triarylamine-based materials as promising catholytes for redox flow batteries.” Journal of Materials Chemistry A, vol. 9, no. 13, Feb. 2021, pp. 8303-8307. https://xlink.rsc.org/?DOI=D0TA11860E.