Chemical Communications

, volume 57 , issue 51 , pages 6268-6271

Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines

Weixing Chen ^{1, 2, 3, 4, 5, 6}

Liu Li ¹

Liu Li ^{1, 2, 3, 4, 5, 6}

Yanxia Zhao ^{1, 2, 3, 4, 5, 6}

Yujie Xue ^{1, 2, 3, 4, 5, 6}

WENHUA XU ^{1, 2, 3, 4, 5, 6}

Nan Li ^{6, 7, 8, 9, 10, 11}

Biao Wu ^{1, 2, 3, 4, 5, 6, 12}

Xiao-Juan Yang ^{1, 2, 3, 4, 5, 6, 12}

Hide authors affiliations Show authors affiliations: 12 affiliations

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, China |

Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education

College of Chemistry and Materials Science

⁴

Northwest University |

⁵

Xi’an 710069

⁶

CHINA |

⁷

State Key Laboratory of Explosion Science and Technology, School of Mechatronical Engineering, Beijing Institute of Technology, Beijing 100081, China |

⁸

State Key Laboratory of Explosion Science and Technology

⁹

School of Mechatronical Engineering

¹⁰

BeiJing Institute of Technology |

¹¹

Beijing 100081 |

¹²

Key Laboratory of Medical Molecule Science and Pharmaceutics Engineering, Ministry of Industry and Information Technology, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China |

Publication type: Journal Article

Publication date: 2021-05-20

Royal Society of Chemistry (RSC)

Chemical Communications

scimago Q1

wos Q2

SJR: 1.037

CiteScore: 7.4

Impact factor: 4.2

ISSN: 13597345, 1364548X

DOI: 10.1039/d1cc00318f

Copy DOI

PubMed ID: 34075952

Materials Chemistry

Metals and Alloys

Surfaces, Coatings and Films

General Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Catalysis

Abstract

Dialumane 1 reacts with pyridines at elevated temperatures through regioselective reductive dehydrogenation of 4-H, affording a unique hexanuclear Al(III) macrocycle [{LAl(pyridyl)}6], which represents the first dialumane-mediated C–H activation of Py and may suggest a new approach toward organometallo supra-molecules by one-pot small molecule activation and self-assembly.

Found

1 citation

Dodonov Vladimir

🥼 🤝

PhD in Chemistry

34 publications, 555 citations, 1 review

h-index: 15

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Coordination Chemistry

Low-valent compounds

Organoelement chemistry

1 citation

Baranov Evgeniy

PhD in Chemistry

247 publications, 3 263 citations

h-index: 29

G. A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences

Research interests

Crystal Chemistry

Organic Chemistry

Organometallic Chemistry

Quantum Chemistry

X-ray diffraction analysis

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GOST |

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GOST Copy

Chen W. et al. Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines // Chemical Communications. 2021. Vol. 57. No. 51. pp. 6268-6271.

GOST all authors (up to 50) Copy

Chen W. et al. Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines // Chemical Communications. 2021. Vol. 57. No. 51. pp. 6268-6271.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1039/d1cc00318f

UR - https://xlink.rsc.org/?DOI=D1CC00318F

TI - Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines

T2 - Chemical Communications

AU - Chen, Weixing

AU - Li, Liu

AU - Liu Li

AU - Zhao, Yanxia

AU - Xue, Yujie

AU - XU, WENHUA

AU - Li, Nan

AU - Wu, Biao

AU - Yang, Xiao-Juan

PY - 2021

DA - 2021/05/20

PB - Royal Society of Chemistry (RSC)

SP - 6268-6271

IS - 51

VL - 57

PMID - 34075952

SN - 1359-7345

SN - 1364-548X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Chen,

author = {Weixing Chen and Liu Li and Liu Li and Yanxia Zhao and Yujie Xue and WENHUA XU and Nan Li and Biao Wu and Xiao-Juan Yang and others},

title = {Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines},

journal = {Chemical Communications},

year = {2021},

volume = {57},

publisher = {Royal Society of Chemistry (RSC)},

month = {may},

url = {https://xlink.rsc.org/?DOI=D1CC00318F},

number = {51},

pages = {6268--6271},

doi = {10.1039/d1cc00318f}

}

MLA

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MLA Copy

Chen, Weixing, et al. “Organometallo-macrocycle assembled through dialumane-mediated C–H activation of pyridines.” Chemical Communications, vol. 57, no. 51, May. 2021, pp. 6268-6271. https://xlink.rsc.org/?DOI=D1CC00318F.

Publisher

Royal Society of Chemistry (RSC)

Journal

Chemical Communications

scimago Q1

wos Q2

SJR

1.037

CiteScore

7.4

Impact factor

4.2

ISSN

13597345 (Print)

1364548X (Electronic)

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