volume 23 issue 15 pages 2816-2824

Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties

Publication typeJournal Article
Publication date2021-03-08
scimago Q2
wos Q2
SJR0.520
CiteScore5.2
Impact factor2.6
ISSN14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Five new salts of the 3,4-dicyano-2-(dicyanomethylene)-5-methyl-6-phenyl-2H-pyridin-1-ide anion (TCPy−) with lithium, sodium, potassium, rubidium and cesium cations were synthesized and structurally characterized by a single-crystal X-ray diffraction method. The solid state photoluminescence characteristics of the prepared salts were studied. The crystallographic features of the crystal packing which are responsible for the emission band position were investigated. Quantum-chemical calculations were carried out to explain the correlation between emission maxima and the crystal structure.
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GOST Copy
Chunikhin S. S. et al. Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties // CrystEngComm. 2021. Vol. 23. No. 15. pp. 2816-2824.
GOST all authors (up to 50) Copy
Chunikhin S. S., Ершов О., Yatsenko A., Тафеенко В. А., Tafeenko V. A., Dmitrieva N. E., Ievlev M. Y. Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties // CrystEngComm. 2021. Vol. 23. No. 15. pp. 2816-2824.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1039/d1ce00028d
UR - https://xlink.rsc.org/?DOI=D1CE00028D
TI - Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties
T2 - CrystEngComm
AU - Chunikhin, Sergey S
AU - Ершов, О.В.
AU - Yatsenko, Alexandr
AU - Тафеенко, В. А.
AU - Tafeenko, Viktor A.
AU - Dmitrieva, Natalia E
AU - Ievlev, Mikhail Yu.
PY - 2021
DA - 2021/03/08
PB - Royal Society of Chemistry (RSC)
SP - 2816-2824
IS - 15
VL - 23
SN - 1466-8033
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Chunikhin,
author = {Sergey S Chunikhin and О.В. Ершов and Alexandr Yatsenko and В. А. Тафеенко and Viktor A. Tafeenko and Natalia E Dmitrieva and Mikhail Yu. Ievlev},
title = {Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties},
journal = {CrystEngComm},
year = {2021},
volume = {23},
publisher = {Royal Society of Chemistry (RSC)},
month = {mar},
url = {https://xlink.rsc.org/?DOI=D1CE00028D},
number = {15},
pages = {2816--2824},
doi = {10.1039/d1ce00028d}
}
MLA
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MLA Copy
Chunikhin, Sergey S., et al. “Alkali metal salts of a tetracyanopyridine (TCPy) derivative: structure characterization and luminescence properties.” CrystEngComm, vol. 23, no. 15, Mar. 2021, pp. 2816-2824. https://xlink.rsc.org/?DOI=D1CE00028D.