Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules
Publication type: Journal Article
Publication date: 2022-01-01
scimago Q2
wos Q2
SJR: 0.520
CiteScore: 5.2
Impact factor: 2.6
ISSN: 14668033
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Novel peroxosolvates of tetraalkylammonium halides Et4N+Cl−·2(H2O2) (1), Et4N+Br−·2(H2O2) (2), Me3(ClCH2CH2)N+Cl−·H2O2 (3) and Me3PhN+Cl−·H2O2 (4) were prepared from concentrated hydrogen peroxide and the corresponding structures were determined by X-ray crystallography. Structures 1 and 2 are formed by globose Et4N+ cations and are the first examples of layers containing H-bonded peroxide molecules. By contrast, 3 and 4 are formed by sufficiently aspherical Me3(ClCH2CH2)N+ and Me3PhN+ units and contain infinitely long hydrogen-bonded peroxide–halide chains.
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Navasardyan M. A. et al. Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules // CrystEngComm. 2022. Vol. 24. No. 1. pp. 38-42.
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Navasardyan M. A., Bezzubov S. I., Medvedev A. G., Prikhodchenko P. V., Churakov A. V. Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules // CrystEngComm. 2022. Vol. 24. No. 1. pp. 38-42.
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TY - JOUR
DO - 10.1039/d1ce01476e
UR - https://xlink.rsc.org/?DOI=D1CE01476E
TI - Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules
T2 - CrystEngComm
AU - Navasardyan, Mger A.
AU - Bezzubov, Stanislav I.
AU - Medvedev, Alexander G.
AU - Prikhodchenko, Petr V.
AU - Churakov, Andrei V.
PY - 2022
DA - 2022/01/01
PB - Royal Society of Chemistry (RSC)
SP - 38-42
IS - 1
VL - 24
SN - 1466-8033
ER -
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@article{2022_Navasardyan,
author = {Mger A. Navasardyan and Stanislav I. Bezzubov and Alexander G. Medvedev and Petr V. Prikhodchenko and Andrei V. Churakov},
title = {Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules},
journal = {CrystEngComm},
year = {2022},
volume = {24},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D1CE01476E},
number = {1},
pages = {38--42},
doi = {10.1039/d1ce01476e}
}
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MLA
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Navasardyan, Mger A., et al. “Novel peroxosolvates of tetraalkylammonium halides: the first case of layers containing hydrogen-bonded peroxide molecules.” CrystEngComm, vol. 24, no. 1, Jan. 2022, pp. 38-42. https://xlink.rsc.org/?DOI=D1CE01476E.