Functionalized triphenylphosphine oxide-based manganese(ii ) complexes for luminescent printing
Xiaomeng Huang
1, 2, 3, 4, 5, 6
,
YANYAN QIN
1, 2, 3, 4, 5, 6
,
Pengfei She
1, 2, 3, 4, 5, 6
,
Haixing Meng
1, 2, 3, 4, 5, 6
,
Shujuan Liu
1, 2, 3, 4, 5, 6
,
X Hu
1, 2, 3, 4, 5, 6
2
State Key Laboratory of Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors
3
Institute of Advanced Materials (IAM) & Institute of Flexible Electronics (Future Technology)
5
Nanjing
|
6
P. R. China
|
Publication type: Journal Article
Publication date: 2021-05-19
scimago Q2
wos Q1
SJR: 0.653
CiteScore: 6.0
Impact factor: 3.3
ISSN: 14779226, 14779234
PubMed ID:
34096946
Inorganic Chemistry
Abstract
Three novel neutral manganese(II) complexes (TPhPONMe2)2MnBr2, (TPhPOOMe)2MnBr2, and (TPhPOCF3)2MnBr2 have been designed and synthesized based on a functionalized Ph3PO ligand. These structures are clarified by single crystal X-ray diffraction analysis, which reveals that they crystallize in centrosymmetric space groups and feature an isolated mononuclear structure with Mn2+ in a tetrahedral environment. The photoluminescence spectra and emission lifetime decay curves of three manganese(II) complexes show distinct green emission (λem = 498–512 nm) and phosphorescence lifetime (τ = 362.0–663.0 μs). The results of DFT calculations indicate that the energy levels of (TPhPONMe2)2MnBr2 and (TPhPOOMe)2MnBr2 are higher than that of (TPhPOCF3)2MnBr2 due to the electron-donating effect of the NMe2 or OMe group, which explains the blue-shift of the emission wavelength and the increase of emission lifetime. Furthermore, the prepared neutral manganese(II) complexes can be used for high-resolution luminescent printing.
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17
Total citations:
17
Citations from 2025:
7
(41.17%)
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GOST
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Huang X. et al. Functionalized triphenylphosphine oxide-based manganese(ii) complexes for luminescent printing // Dalton Transactions. 2021. Vol. 50. No. 25. pp. 8831-8836.
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Huang X., QIN Y., She P., Meng H., Liu S., Hu X. Functionalized triphenylphosphine oxide-based manganese(ii) complexes for luminescent printing // Dalton Transactions. 2021. Vol. 50. No. 25. pp. 8831-8836.
Cite this
RIS
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TY - JOUR
DO - 10.1039/d1dt00914a
UR - https://xlink.rsc.org/?DOI=D1DT00914A
TI - Functionalized triphenylphosphine oxide-based manganese(ii) complexes for luminescent printing
T2 - Dalton Transactions
AU - Huang, Xiaomeng
AU - QIN, YANYAN
AU - She, Pengfei
AU - Meng, Haixing
AU - Liu, Shujuan
AU - Hu, X
PY - 2021
DA - 2021/05/19
PB - Royal Society of Chemistry (RSC)
SP - 8831-8836
IS - 25
VL - 50
PMID - 34096946
SN - 1477-9226
SN - 1477-9234
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Huang,
author = {Xiaomeng Huang and YANYAN QIN and Pengfei She and Haixing Meng and Shujuan Liu and X Hu},
title = {Functionalized triphenylphosphine oxide-based manganese(ii) complexes for luminescent printing},
journal = {Dalton Transactions},
year = {2021},
volume = {50},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=D1DT00914A},
number = {25},
pages = {8831--8836},
doi = {10.1039/d1dt00914a}
}
Cite this
MLA
Copy
Huang, Xiaomeng, et al. “Functionalized triphenylphosphine oxide-based manganese(ii) complexes for luminescent printing.” Dalton Transactions, vol. 50, no. 25, May. 2021, pp. 8831-8836. https://xlink.rsc.org/?DOI=D1DT00914A.
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