Dalton Transactions, volume 50, issue 39, pages 13680-13685

Dipole fluctuation and structural phase transition in hydrogen-bonding molecular assemblies of mononuclear Cu^II complexes with polar fluorobenzoate ligands

Kiyonori Takahashi ¹

Yuji Miyazaki ²

Shin-ichiro Noro ³

Motohiro Nakano ²

Takayoshi Nakamura ¹

Tomoyuki Akutagawa ⁴

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Research Institute for Electronic Science, Hokkaido University, Sapporo, Hokkaido 001-0020, Japan |

Research Center for Thermal and Entropic Science, Graduate School of Science, Osaka University, Toyonaka, Japan |

Faculty of Environmental Earth Science, Hokkaido University, Sapporo, Japan |

⁴

Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai, Miyagi 980-8577, Japan |

Publication type: Journal Article

Publication date: 2021-08-18

Royal Society of Chemistry (RSC)

Journal: Dalton Transactions

scimago Q1

SJR: 0.697

CiteScore: 6.6

Impact factor: 3.5

ISSN: 14779226, 14779234

DOI: 10.1039/d1dt02118d

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Inorganic Chemistry

Abstract

An effective approach to construct dynamic motional space in molecular crystals is accomplished by combining hydrogen-bonding chains with dipole–dipole interactions in mononuclear Cu^II complexes.

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Publisher

Royal Society of Chemistry (RSC)

Journal

Dalton Transactions

scimago Q1

SJR

0.697

CiteScore

6.6

Impact factor

3.5

ISSN

14779226 (Print)

14779234 (Electronic)

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Dipole fluctuation and structural phase transition in hydrogen-bonding molecular assemblies of mononuclear Cu^II complexes with polar fluorobenzoate ligands

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Dipole fluctuation and structural phase transition in hydrogen-bonding molecular assemblies of mononuclear CuII complexes with polar fluorobenzoate ligands

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Dipole fluctuation and structural phase transition in hydrogen-bonding molecular assemblies of mononuclear Cu^II complexes with polar fluorobenzoate ligands