Green Chemistry

, volume 23 , issue 5 , pages 1960-1964

Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation

Pengqian Luan ^{1, 2, 3, 4, 5}

Yunting Liu ^{1, 2, 3, 4, 5, 6, 7}

Yongxing Li ^{1, 2, 3, 4, 5}

Ran Chen ^{1, 2, 3, 4, 5}

Chen Huang ^{1, 2, 3, 4, 5}

Jing Gao ^{1, 2, 3, 4, 5}

Frank Hollmann ^{8, 9, 10, 11, 12}

Yanjun Jiang ^{1, 2, 3, 4, 5}

Hide authors affiliations Show authors affiliations: 12 affiliations

School of Chemical Engineering and Technology, HeBei University of Technology, Tianjin 300130, China |

School of Chemical Engineering and Technology

Hebei university of Technology |

⁴

Tianjin 300130 |

⁵

CHINA |

⁶

Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization (Tianjin University of Science and Technology), Tianjin 300457, China |

⁷

Tianjin Key Laboratory of Brine Chemical Engineering and Resource Eco-utilization (Tianjin University of Science and Technology) |

⁸

Department of Biotechnology, Delft University of Technology, 2629 HZ Delft, The Netherlands |

⁹

Department of Biotechnology

¹⁰

DELFT University of Technology |

¹¹

2629 HZ Delft |

¹²

the Netherlands |

Publication type: Journal Article

Publication date: 2021-02-22

Royal Society of Chemistry (RSC)

Green Chemistry

scimago Q1

wos Q1

SJR: 1.928

CiteScore: 16.1

Impact factor: 9.2

ISSN: 14639262, 14639270

DOI: 10.1039/d1gc00372k

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Environmental Chemistry

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Abstract

An aqueous chemoenzymatic cascade reaction combining Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation (AH) was developed for enantioselective synthesis of tertiary α-aryl cycloketones in good yields and excellent enantioselectivities. The stereopreference of the enzyme in AH of α-aryl cyclohexenones was studied. An enantiocomplementary enzyme was obtained by site-directed mutation.

Found

1 citation

Nikoshvili Linda

PhD in Chemistry, associate professor

80 publications, 956 citations, 11 reviews

h-index: 18

Tver State Technical University

Research interests

Catalysis

Catalytic reduction

Heterogeneous catalysis

Polymer sorbents

Polymers and composites

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GOST |

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GOST Copy

Luan P. et al. Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation // Green Chemistry. 2021. Vol. 23. No. 5. pp. 1960-1964.

GOST all authors (up to 50) Copy

Luan P., Liu Y., Li Y., Chen R., Huang C., Gao J., Hollmann F., Jiang Y. Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation // Green Chemistry. 2021. Vol. 23. No. 5. pp. 1960-1964.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1039/d1gc00372k

UR - https://xlink.rsc.org/?DOI=D1GC00372K

TI - Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation

T2 - Green Chemistry

AU - Luan, Pengqian

AU - Liu, Yunting

AU - Li, Yongxing

AU - Chen, Ran

AU - Huang, Chen

AU - Gao, Jing

AU - Hollmann, Frank

AU - Jiang, Yanjun

PY - 2021

DA - 2021/02/22

PB - Royal Society of Chemistry (RSC)

SP - 1960-1964

IS - 5

VL - 23

SN - 1463-9262

SN - 1463-9270

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2021_Luan,

author = {Pengqian Luan and Yunting Liu and Yongxing Li and Ran Chen and Chen Huang and Jing Gao and Frank Hollmann and Yanjun Jiang},

title = {Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation},

journal = {Green Chemistry},

year = {2021},

volume = {23},

publisher = {Royal Society of Chemistry (RSC)},

month = {feb},

url = {https://xlink.rsc.org/?DOI=D1GC00372K},

number = {5},

pages = {1960--1964},

doi = {10.1039/d1gc00372k}

}

MLA

Cite this

MLA Copy

Luan, Pengqian, et al. “Aqueous chemoenzymatic one-pot enantioselective synthesis of tertiary α-aryl cycloketones via Pd-catalyzed C–C formation and enzymatic CC asymmetric hydrogenation.” Green Chemistry, vol. 23, no. 5, Feb. 2021, pp. 1960-1964. https://xlink.rsc.org/?DOI=D1GC00372K.

Publisher

Royal Society of Chemistry (RSC)

Journal

Green Chemistry

scimago Q1

wos Q1

SJR

1.928

CiteScore

16.1

Impact factor

9.2

ISSN

14639262 (Print)

14639270 (Electronic)

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